{"id":"W2003138282","doi":"10.1021/ed800161a","title":"The Mechanochemical Reaction of Palladium(II) Chloride with a Bidentate Phosphine","year":2010,"lang":"en","type":"article","venue":"Journal of Chemical Education","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"University of Victoria","keywords":"Palladium; Phosphine; Chemistry; Denticity; Metalation; Methylene; Chloride; Catalysis; Ligand (biochemistry); Coupling reaction; Pentane; Inorganic chemistry; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001392942,0.0001848738,0.0001133953,0.000113151,0.0001733961,0.0002765663,0.000374173,0.0002287811,0.002705748],"category_scores_gemma":[0.0001985988,0.0001402817,0.0001212916,0.00007780467,0.0002947081,0.0003152899,0.0003743427,0.0002569778,0.0005480048],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002444891,"about_ca_system_score_gemma":0.0001491781,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002566467,"about_ca_topic_score_gemma":0.0003173318,"domain_scores_codex":[0.9998525,0.00001404057,0.000006589296,0.00004721041,0.00004678113,0.00003294642],"domain_scores_gemma":[0.9999341,0.00001878304,0.00001439296,0.00001547947,0.000006109136,0.00001111314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008862014,0.00003802501,0.0001330331,0.0000964991,0.000005131697,0.000134939,0.00004575062,0.00016121,0.9925517,0.002119097,0.0001550233,0.004471017],"study_design_scores_gemma":[0.0000194263,0.0002588465,0.0003314867,0.000001653949,0.000002765834,0.0001419857,0.00002026903,0.0006270678,0.9949716,0.0001721245,0.003446834,0.000005889],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9765825,0.0004182548,0.008428873,0.0003038746,0.0001104233,0.00004595914,0.0001012487,0.0002683242,0.01374048],"genre_scores_gemma":[0.9930713,0.0001259996,0.002858182,0.00007433957,0.00001391295,0.00002034402,0.00005751139,0.00002245915,0.003755985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002705748,"threshold_uncertainty_score":0.009051621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004745716251978523,"score_gpt":0.2373782951981721,"score_spread":0.2326325789461935,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}