{"id":"W2003274250","doi":"10.1002/anie.200700801","title":"Synthesis and Characterization of Tantalum(V) Boronate Clusters: Multifunctional Lewis Acid Cages for Binding Guests","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; University of Ottawa; Université Laval","funders":"","keywords":"Tantalum; Lewis acids and bases; Chemistry; Ligand (biochemistry); Characterization (materials science); Stereochemistry; Combinatorial chemistry; Organic chemistry; Nanotechnology; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000287152,0.0001636473,0.0002040252,0.0001562383,0.00009271795,0.00004350024,0.0001473347,0.0001143419,0.003127155],"category_scores_gemma":[0.0002237838,0.0001697755,0.0001232718,0.00009402474,0.00007746537,0.0003350227,0.00005513624,0.00006865665,0.00000545162],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001297712,"about_ca_system_score_gemma":0.00001927146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001856883,"about_ca_topic_score_gemma":0.00001587426,"domain_scores_codex":[0.9988058,0.000005201235,0.0003897952,0.0002993368,0.0003234603,0.0001764265],"domain_scores_gemma":[0.9990485,0.0002565546,0.0002861723,0.000131993,0.0002117502,0.00006503175],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001101788,0.00008831033,0.0008150728,0.00009483844,0.0001643928,0.00000145289,0.000103127,5.679644e-7,0.9813239,0.0001071364,0.00009961366,0.01709143],"study_design_scores_gemma":[0.000372689,0.00001153309,0.00515441,0.00009930163,0.00008696219,0.00001305482,0.0001790897,0.0001602656,0.9845349,0.00008096114,0.009137455,0.0001693959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826196,0.00006557511,0.01140623,0.0003691193,0.0005403071,0.00009519895,0.001118933,0.0000558633,0.003729207],"genre_scores_gemma":[0.9952236,0.00008782061,0.0004699168,0.00003636169,0.001015004,0.00005356962,0.002097308,0.00002558585,0.0009908663],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01692203,"threshold_uncertainty_score":0.9977841,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01672199752041987,"score_gpt":0.24816524609964,"score_spread":0.2314432485792201,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}