{"id":"W2003377478","doi":"10.1039/c000359j","title":"Vibrationally excited ultrafast thermodynamic phase transitions at the water/air interface","year":2010,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Excited state; Fluence; Laser; Nanosecond; Picosecond; Adiabatic process; Materials science; Phase (matter); Ultrashort pulse; Molecular physics; Chemistry; Atomic physics; Optics; Thermodynamics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008065677,0.0001113734,0.00009941422,0.00006300668,0.0001612578,0.0001857721,0.0001959536,0.0001369739,0.001080243],"category_scores_gemma":[0.0002121821,0.0001332827,0.00009845271,0.00006358201,0.0004140614,0.0004362685,0.0002938921,0.0002923389,0.0001273737],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002976816,"about_ca_system_score_gemma":0.0001462648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005787666,"about_ca_topic_score_gemma":0.0007137726,"domain_scores_codex":[0.9999599,0.000003070889,0.000001068224,0.000006737352,0.00001646132,0.00001271602],"domain_scores_gemma":[0.9999434,0.00002833053,0.00001158603,0.000004889583,0.000006001387,0.000005901918],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004429452,0.00002002181,0.0004881535,0.00004637814,0.000003367563,0.00004324509,0.00006002143,0.00408888,0.9907232,0.001722676,0.00004049681,0.002719201],"study_design_scores_gemma":[0.00002493647,0.0001278328,0.003272336,0.000004899267,0.000006521298,0.00005809887,0.00008001161,0.07522583,0.9186133,0.001440057,0.001136226,0.00000984913],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943501,0.000130563,0.004602818,0.00002631395,0.000005325111,0.000004916231,0.00001558265,0.00003325596,0.0008312206],"genre_scores_gemma":[0.9978166,0.00007102938,0.001740331,0.000006574249,0.000002126447,0.000005873145,0.00001582614,0.000007377331,0.0003342338],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001080243,"threshold_uncertainty_score":0.00361377,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006310350387738121,"score_gpt":0.2599383062117429,"score_spread":0.2536279558240048,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}