{"id":"W2003409443","doi":"10.1063/1.4875035","title":"Excited state dynamics in SO2. I. Bound state relaxation studied by time-resolved photoelectron-photoion coincidence spectroscopy","year":2014,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; University of Ottawa; National Research Council Canada","funders":"","keywords":"Excited state; Intersystem crossing; Chemistry; Atomic physics; Relaxation (psychology); Wave packet; Spectroscopy; Photoionization; Excitation; Ionization; Physics; Singlet state; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005616254,0.0002904769,0.000533539,0.00003302865,0.0001192765,0.00005018685,0.0003951663,0.00004217515,0.00003897442],"category_scores_gemma":[0.00005011953,0.0002112885,0.0001539654,0.0003428003,0.000208558,0.0002249167,0.00009208055,0.0007596946,0.00001675259],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00036392,"about_ca_system_score_gemma":0.00005890807,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001749251,"about_ca_topic_score_gemma":0.000006167684,"domain_scores_codex":[0.9980646,0.0001314208,0.0006628387,0.0002003356,0.000447465,0.0004933173],"domain_scores_gemma":[0.9983611,0.0004347908,0.0007037588,0.0002306445,0.000164166,0.0001055497],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006187008,0.0003019459,0.0007843519,0.00001175326,0.0001400886,0.000001182198,0.0004023539,0.0001461344,0.992408,0.0005025797,0.003352626,0.001330329],"study_design_scores_gemma":[0.001227429,0.0002645747,0.00008054895,0.00007253837,0.00006963324,0.000002946214,0.00009043539,0.01446602,0.893006,0.09019884,0.0002611139,0.0002599602],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9751199,0.0001532401,0.02315748,0.0003058971,0.00007193228,0.0001803278,0.00002877855,0.00001718986,0.0009651873],"genre_scores_gemma":[0.9992046,0.00005054667,0.0001904689,0.00009762042,0.0002688838,0.000006386532,0.00003196528,0.00003179167,0.0001176915],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09940199,"threshold_uncertainty_score":0.8616093,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005523783738866697,"score_gpt":0.237982095634027,"score_spread":0.2324583118951603,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}