{"id":"W2003589691","doi":"10.1002/cphc.200600686","title":"Luminescence and Stability of Aqueous Thioalkyl Acid Capped CdSe/ZnS Quantum Dots Correlated to Ligand Ionization","year":2007,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Quantum Dots Synthesis And Properties","field":"Materials Science","cited_by":135,"is_retracted":false,"has_abstract":true,"ca_institutions":"Amgen (Canada); University of Toronto","funders":"","keywords":"Hypsochromic shift; Bathochromic shift; Chemistry; Ligand (biochemistry); Quantum yield; Quantum dot; Photochemistry; Luminescence; Passivation; Inorganic chemistry; Materials science; Nanotechnology; Organic chemistry; Fluorescence","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000886386,0.0001971317,0.00031976,0.00005959282,0.0001209199,0.00005359866,0.0002109939,0.0001263543,0.0001418493],"category_scores_gemma":[0.0004455899,0.0001618311,0.00004319716,0.000270093,0.0001988175,0.0001857624,0.0001086678,0.00009024166,0.00006556022],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004320905,"about_ca_system_score_gemma":0.00005690046,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001076658,"about_ca_topic_score_gemma":0.0000237293,"domain_scores_codex":[0.9984787,0.00004113097,0.0004479552,0.0004085649,0.000280256,0.0003434271],"domain_scores_gemma":[0.9989681,0.000121715,0.0001614439,0.0003746633,0.0002146726,0.0001593848],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001557175,0.0000803091,0.002300727,0.0001026781,0.000005231047,0.000003309104,0.001465547,0.000002753506,0.9939787,0.0001928469,0.0001377407,0.001574378],"study_design_scores_gemma":[0.0002289163,0.00008972704,0.003210489,0.000083561,0.00001592634,0.000009030763,0.0003601474,0.0004150456,0.9948809,0.0001227256,0.0003718234,0.0002117788],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968885,0.0007533362,0.0009082307,0.0001686856,0.0002403428,0.0002650629,0.00001355684,0.00008604346,0.0006762794],"genre_scores_gemma":[0.998974,0.00003677165,0.000737365,0.0001011675,0.00006366375,0.000008372138,0.000005619285,0.00002098029,0.00005210074],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002085498,"threshold_uncertainty_score":0.659928,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01963665526250557,"score_gpt":0.2370650855328719,"score_spread":0.2174284302703663,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}