{"id":"W2003611446","doi":"10.1021/ja111418j","title":"Monofunctionalized Pillar[5]arene as a Host for Alkanediamines","year":2011,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":503,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"King Abdulaziz City for Science and Technology; World Anti-Doping Agency; Northwestern University","keywords":"Pillar; Chemistry; Rotaxane; Host (biology); Superstructure; Nanotechnology; Combinatorial chemistry; Stereochemistry; Molecule; Supramolecular chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001006545,0.0002630567,0.0001952973,0.0001845821,0.0001593667,0.0003130477,0.0003866688,0.0002253798,0.001850187],"category_scores_gemma":[0.0001129426,0.0001558744,0.0001121536,0.0001052931,0.0001461969,0.0002774608,0.0002826139,0.000260025,0.0005801711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002714068,"about_ca_system_score_gemma":0.0001030184,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002122517,"about_ca_topic_score_gemma":0.0004519984,"domain_scores_codex":[0.9999101,0.00001526113,0.000007927062,0.00002092558,0.00002576206,0.00001993947],"domain_scores_gemma":[0.9999348,0.00001130477,0.00001693703,0.00001149164,0.000007557875,0.00001799734],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006500407,0.00002222664,0.00006050448,0.0000582984,0.000005253906,0.00008873098,0.00002002485,0.0002318454,0.9959345,0.001220056,0.00008582052,0.002207682],"study_design_scores_gemma":[0.00002116202,0.0002513429,0.0005923447,0.000006212865,0.000008732714,0.0001572008,0.00001138761,0.001455528,0.9914286,0.00009656674,0.005960794,0.00001023601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865479,0.001275575,0.004557122,0.00008342195,0.00004413128,0.00006476494,0.0001996933,0.0002864431,0.006940948],"genre_scores_gemma":[0.991725,0.0005710858,0.004634929,0.00003182073,0.00001215397,0.00003753065,0.0001468065,0.00002682013,0.002813767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001850187,"threshold_uncertainty_score":0.006189466,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02142697580052495,"score_gpt":0.2477356846398006,"score_spread":0.2263087088392757,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}