{"id":"W2003714070","doi":"10.1139/v05-208","title":"Dynamics of the transient species generated upon photolysis of diarylmethanes within zeolites Deprotonation and oxidation reactions","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Deprotonation; Carbocation; Radical; Radical ion; Photochemistry; Flash photolysis; Oxidizing agent; Inorganic chemistry; Photodissociation; Reaction rate constant; Organic chemistry; Kinetics; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001284678,0.0001543136,0.0001501319,0.000206503,0.0001296851,0.0002487983,0.0001969179,0.0001836551,0.001653393],"category_scores_gemma":[0.0002441665,0.0001020035,0.0001533799,0.0001346056,0.0002146682,0.0003225349,0.0001163555,0.0003598899,0.0001703477],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002962128,"about_ca_system_score_gemma":0.000103982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009323978,"about_ca_topic_score_gemma":0.0007838883,"domain_scores_codex":[0.9999399,0.000004756181,0.000002277723,0.00001368813,0.00001832742,0.00002095714],"domain_scores_gemma":[0.9998473,0.00005906444,0.00003946483,0.000007106165,0.00002617631,0.0000208816],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001709039,0.00001425777,0.0006217469,0.00004383471,0.000007605781,0.00007380269,0.00007600724,0.0002852024,0.9968066,0.0001699097,0.00002517924,0.001704945],"study_design_scores_gemma":[0.00001980705,0.0002133404,0.007266972,0.000005279404,0.00001009302,0.0001026061,0.00008900368,0.002670016,0.9888296,0.00008485617,0.0006989934,0.000009469907],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997876,0.0002954159,0.001200801,0.00001535842,0.00000414659,0.00001261063,0.0001118639,0.00002241362,0.0004613205],"genre_scores_gemma":[0.9983754,0.000175477,0.0004271725,0.000009739276,0.000002315793,0.00001002066,0.0001542361,0.000006680944,0.0008388966],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001653393,"threshold_uncertainty_score":0.005531192,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008185693395872799,"score_gpt":0.1977334354503207,"score_spread":0.1895477420544479,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}