{"id":"W2003730334","doi":"10.1021/om020295k","title":"Binuclear Fluorovinyl Complexes of Iridium:  Transformation of an Iridium-Bound Trifluorovinyl Group into a <i>trans</i>-[Ir−C(F)C(F)CH<sub>3</sub>] Moiety","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Iridium; Moiety; Methyllithium; Substituent; Ligand (biochemistry); Hydride; Methyl group; Stereochemistry; Medicinal chemistry; Group (periodic table); Oxidative addition; Protonation; Metal; Fluoride; Trifluoromethyl; Organic chemistry; Alkyl; Ion; Inorganic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001445759,0.0003580819,0.0002550042,0.0001588522,0.0001879166,0.0003178068,0.0006615546,0.0005073768,0.001241352],"category_scores_gemma":[0.0002459473,0.0001884726,0.0001491294,0.0001772119,0.0002103214,0.0003364954,0.0004099671,0.000406963,0.0002134377],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005622191,"about_ca_system_score_gemma":0.0002687664,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001536151,"about_ca_topic_score_gemma":0.002671813,"domain_scores_codex":[0.9998569,0.00002460849,0.000007814235,0.00002283008,0.00002860952,0.0000590849],"domain_scores_gemma":[0.9999304,0.00001008118,0.00001982126,0.000008067061,0.00001126935,0.00002034411],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003107619,0.00004385992,0.0001040241,0.0001495607,0.00001844788,0.00007872261,0.0000777829,0.000344098,0.9947278,0.001398111,0.0001722095,0.002574664],"study_design_scores_gemma":[0.00008332577,0.0005525228,0.0006132507,0.00001199159,0.0000193566,0.0001508554,0.0000308443,0.000986049,0.9939947,0.0001277028,0.003409752,0.0000196844],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919665,0.0007115324,0.003215228,0.00006627978,0.00003993141,0.0000345185,0.00009147316,0.0001138847,0.003760676],"genre_scores_gemma":[0.9947184,0.000374548,0.002331466,0.00005085216,0.000005488582,0.00002696859,0.0001313683,0.00003162129,0.002329335],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001536151,"threshold_uncertainty_score":0.004152775,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04993696453692655,"score_gpt":0.3206741592678776,"score_spread":0.2707371947309511,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}