{"id":"W2004092781","doi":"10.1002/chem.200701621","title":"Pd‐Catalyzed Aryl Amination Mediated by Well Defined, N‐Heterocyclic Carbene (NHC)–Pd Precatalysts, PEPPSI","year":2008,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":238,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Carbene; Aryl; Amination; Chemistry; Catalysis; Combinatorial chemistry; Palladium; Organic chemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004570562,0.0005990076,0.0004987951,0.00008887556,0.0007953416,0.0002651311,0.0009393516,0.0001872716,0.002123353],"category_scores_gemma":[0.0006373417,0.0006348084,0.0003858125,0.0003406938,0.0003724973,0.0003555531,0.000224645,0.001429843,0.0008019924],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004975752,"about_ca_system_score_gemma":0.0001576681,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002303213,"about_ca_topic_score_gemma":0.000002068064,"domain_scores_codex":[0.996581,0.00001048681,0.001097597,0.0007624825,0.0007646332,0.0007838275],"domain_scores_gemma":[0.9970825,0.0001854968,0.0007926773,0.0009642536,0.0003012132,0.0006738023],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008203668,0.0002883624,0.001004821,0.0001329866,0.0001507952,0.0006074752,0.0003406421,0.0000356299,0.9826385,4.486843e-7,0.01416794,0.0005503294],"study_design_scores_gemma":[0.002830562,0.00001734978,0.0009189037,0.0001756201,0.0001699063,0.009064017,0.0002508421,0.001075607,0.9564114,0.00001001309,0.02828405,0.000791746],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9832731,0.0009109824,0.00009381925,0.000177778,0.0002269374,0.0000770554,0.0001975791,0.0003210865,0.01472159],"genre_scores_gemma":[0.9857833,0.0005124699,0.00005659245,0.00004373335,0.0007939209,0.00001025713,0.002037577,0.0001866383,0.01057544],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02622715,"threshold_uncertainty_score":0.999976,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01216393217958227,"score_gpt":0.2165282559317229,"score_spread":0.2043643237521406,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}