{"id":"W2004534201","doi":"10.1016/s0008-6215(03)00149-6","title":"Synthesis of S-linked thiooligosaccharide analogues of Nod factors: synthesis of new protected thiodisaccharide and thiotrisaccharide intermediates","year":2003,"lang":"en","type":"article","venue":"Carbohydrate Research","topic":"Legume Nitrogen Fixing Symbiosis","field":"Agricultural and Biological Sciences","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Anomer; Disaccharide; Glycosylation; Glycosyl; Glycosyl donor; Stereochemistry; Yield (engineering); Protecting group; Carbohydrate synthesis; Stereoselectivity; Catalysis; Organic chemistry; Carbohydrate; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001883678,0.0003070495,0.0008369201,0.0002341782,0.0001560974,0.00005072061,0.0007402911,0.0003139151,0.0002409877],"category_scores_gemma":[0.007509029,0.0001425532,0.0002337133,0.001633695,0.0005851797,0.0002176418,0.000233234,0.0004449113,0.00000857332],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000574108,"about_ca_system_score_gemma":0.0001555292,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005041363,"about_ca_topic_score_gemma":0.0003401946,"domain_scores_codex":[0.9961601,0.000840015,0.0008476579,0.0005709809,0.0009116147,0.0006696681],"domain_scores_gemma":[0.9942161,0.004153247,0.0004077412,0.0002849319,0.0006573357,0.0002806567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000695124,0.0001344574,0.03164459,0.0001404962,0.0001268993,0.000003409714,0.0005524931,3.251081e-7,0.9641627,0.0003727672,0.00007360655,0.002718755],"study_design_scores_gemma":[0.0001171355,0.0002259384,0.03444977,0.0002857431,0.00005920708,0.000002423688,0.001326306,0.0000196215,0.9618121,0.001471264,0.00001766715,0.0002128503],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979711,0.0005223805,0.000001196202,0.0002583649,0.00005782763,0.0006172265,0.0001941055,0.00004265964,0.0003351069],"genre_scores_gemma":[0.9993529,0.0002237214,0.000232337,0.000007775103,0.00005881618,0.00006384612,0.00001125063,0.000006605208,0.00004277302],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005625352,"threshold_uncertainty_score":0.8989552,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05649368971826956,"score_gpt":0.2854285361060344,"score_spread":0.2289348463877648,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}