{"id":"W2004535216","doi":"10.1002/1521-3773(20001103)39:21<3933::aid-anie3933>3.0.co;2-w","title":"A Blue Luminescent Starburst Molecule and Its Orange Luminescent Trinuclear PdII Complex: 1,3,5-tris(7-azaindol-1-yl)benzene (tabH) and [PdII3(tab)2Cl4]","year":2000,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Tris; Benzene; Luminescence; Chelation; Ligand (biochemistry); Chemistry; Molecule; Ion; Orange (colour); Bridging ligand; Photochemistry; Crystallography; Stereochemistry; Inorganic chemistry; Materials science; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002125972,0.0003263886,0.000290894,0.0001895449,0.000118446,0.000163693,0.0002712635,0.0001681498,0.001623796],"category_scores_gemma":[0.0001101027,0.0003481996,0.00007373005,0.0002306275,0.00008021243,0.000400758,0.0001082928,0.0003380192,0.0001190361],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002966635,"about_ca_system_score_gemma":0.00002625656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005039432,"about_ca_topic_score_gemma":0.00001930579,"domain_scores_codex":[0.9980164,0.0000285892,0.0004105974,0.0004573644,0.0006445094,0.0004425747],"domain_scores_gemma":[0.9991774,0.00009414198,0.00006309861,0.0002206436,0.0002014607,0.0002432624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002765782,0.0003445584,0.0005976134,0.0004155413,0.0003961402,0.0001373988,0.001480667,0.00009005135,0.9465089,0.0002163981,0.0450149,0.004521206],"study_design_scores_gemma":[0.001991249,0.00007240139,0.002638434,0.0001613525,0.00003982137,0.00008852774,0.0001439039,0.008797298,0.9394991,0.00001916178,0.04610128,0.0004473992],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916599,0.001076008,0.0001633698,0.001066913,0.0006300114,0.0003965317,0.0002756272,0.000320253,0.004411378],"genre_scores_gemma":[0.9949359,0.00171938,0.0001752944,0.0001563997,0.001743392,0.00004058545,0.0004040496,0.00008728804,0.0007376554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008707247,"threshold_uncertainty_score":0.999897,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0150385511246835,"score_gpt":0.2406876092270243,"score_spread":0.2256490581023408,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}