{"id":"W2004733797","doi":"10.1021/om000639b","title":"Methylene-Bridged Heterobinuclear Complexes of Iridium and Ruthenium:  Models for Bimetallic Fischer−Tropsch Catalysts","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Methylene; Diazomethane; Medicinal chemistry; Acrylonitrile; Acetonitrile; Ethylene; Adduct; Ligand (biochemistry); Protonation; Methylene bridge; Ruthenium; Indene; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002461929,0.0002971417,0.0005819895,0.0002110351,0.0001359822,0.00005499701,0.0003660699,0.0001702487,0.002758169],"category_scores_gemma":[0.00005940377,0.0002874777,0.0002766508,0.0006613492,0.000153181,0.0002349948,0.00007826037,0.0001449162,0.00006070566],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005242083,"about_ca_system_score_gemma":0.00004494485,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006323913,"about_ca_topic_score_gemma":0.000008803696,"domain_scores_codex":[0.99825,0.00002913785,0.0005562897,0.0004815464,0.0003349775,0.0003480373],"domain_scores_gemma":[0.9987929,0.0001377227,0.0001999601,0.0005458448,0.0001379133,0.0001856864],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001867016,0.0005521788,0.0001876499,0.0005257143,0.001379694,0.00000492069,0.001119178,0.001007777,0.9514077,0.002931634,0.0007473428,0.03994955],"study_design_scores_gemma":[0.001995548,0.00007866487,0.0001142086,0.0000244029,0.0006254878,0.00002643873,0.0002314887,0.0127263,0.9369343,0.001162641,0.04540776,0.0006727684],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878302,0.001043941,0.00152737,0.0002063678,0.00002455613,0.0001629827,0.000260564,0.000100857,0.008843223],"genre_scores_gemma":[0.9901212,0.0003877794,0.002579342,0.00009323593,0.00006932906,0.00002904455,0.0003434915,0.00007948688,0.006297097],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04466042,"threshold_uncertainty_score":0.9999577,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01717946599241366,"score_gpt":0.2280032534445833,"score_spread":0.2108237874521696,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}