{"id":"W2004821597","doi":"10.1021/ol801232f","title":"Protecting Group Free Glycosidations Using <i>p</i>-Toluenesulfonohydrazide Donors","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Protecting group; Glycosyl; Azide; Oxazoline; Pyranose; Glycosyl donor; Residue (chemistry); Glycoside; Stereochemistry; Alcohol; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001170509,0.0002642734,0.0002439478,0.00005379063,0.0006030105,0.00004840827,0.0004466218,0.0001422953,0.001404179],"category_scores_gemma":[0.0002799424,0.0002885547,0.0001405065,0.0003184493,0.0001304982,0.0002144281,0.0001415763,0.0003733999,0.00005448626],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002471127,"about_ca_system_score_gemma":0.0000609428,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001977409,"about_ca_topic_score_gemma":0.000021667,"domain_scores_codex":[0.9984938,0.00002767282,0.0003477555,0.0004484494,0.000249585,0.0004327306],"domain_scores_gemma":[0.9987794,0.000133736,0.0001584316,0.0007726619,0.00003040698,0.0001254275],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001202229,0.00003899587,0.001220422,0.00005406794,0.0000450918,0.00008616487,0.0003194899,0.00004663248,0.9973432,0.000005401044,0.0007128394,0.0001156746],"study_design_scores_gemma":[0.000451055,0.000002941012,0.00006543487,0.0000497543,0.00004443487,0.0002572479,0.0001286004,0.0002577363,0.9975898,0.00002840288,0.0007654522,0.0003591352],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995702,0.00003826998,0.001012534,0.0009245265,0.0001031853,0.00007583293,0.00001962771,0.0002497254,0.001874322],"genre_scores_gemma":[0.9972901,0.0000142,0.001325223,0.000576806,0.000548793,0.00002359714,0.00002638182,0.00006864127,0.0001262057],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001748116,"threshold_uncertainty_score":0.9999567,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0202099475185026,"score_gpt":0.2056189168171285,"score_spread":0.1854089692986259,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}