{"id":"W2004821597","doi":"10.1021/ol801232f","title":"Protecting Group Free Glycosidations Using <i>p</i>-Toluenesulfonohydrazide Donors","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Protecting group; Glycosyl; Azide; Oxazoline; Pyranose; Glycosyl donor; Residue (chemistry); Glycoside; Stereochemistry; Alcohol; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001389762,0.0004360155,0.0002300369,0.0001048523,0.0001259388,0.0001846447,0.0002499529,0.0001452023,0.001180353],"category_scores_gemma":[0.0001304246,0.0001324739,0.0001386788,0.0001490683,0.0002485273,0.0002401263,0.0002358393,0.0003693341,0.000341575],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003342853,"about_ca_system_score_gemma":0.0002515278,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006359251,"about_ca_topic_score_gemma":0.0008983839,"domain_scores_codex":[0.9999111,0.00001748581,0.000006076574,0.00001696047,0.00002191821,0.00002645195],"domain_scores_gemma":[0.9999074,0.00001523824,0.00003131237,0.00001605624,0.00001240198,0.00001758821],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005494497,0.000008228705,0.00007050252,0.00003725447,0.000004381253,0.00006504945,0.00003030582,0.00007806083,0.9974352,0.0005434513,0.00005654576,0.001616176],"study_design_scores_gemma":[0.000005602627,0.00005387766,0.0001911229,0.000001259363,0.000003805957,0.00005319641,0.000007208902,0.000106447,0.998678,0.00003874616,0.0008586813,0.000002015062],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9739714,0.001003529,0.0177515,0.00009373487,0.00004627026,0.00006105462,0.000291894,0.0002248409,0.006555736],"genre_scores_gemma":[0.9918372,0.0008271767,0.004733338,0.0000299082,0.000009616978,0.00002951891,0.0002470921,0.00003284857,0.00225337],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001180353,"threshold_uncertainty_score":0.003948689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0202099475185026,"score_gpt":0.2056189168171285,"score_spread":0.1854089692986259,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}