{"id":"W2004947786","doi":"10.1002/chem.201102404","title":"Alkali‐Metal‐Ion Catalysis and Inhibition in the Nucleophilic Displacement Reaction of Y‐Substituted Phenyl Diphenylphosphinates and Diphenylphosphinothioates with Alkali‐Metal Ethoxides: Effect of Changing the Electrophilic Center from PO to PS","year":2011,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Reactivity (psychology); Nucleophile; Alkali metal; Medicinal chemistry; Reaction rate constant; Substituent; Inorganic chemistry; Catalysis; Kinetics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001155843,0.0003936306,0.000450787,0.000086651,0.0001954218,0.00007589396,0.0003115016,0.00008653173,0.0001632075],"category_scores_gemma":[0.0002380551,0.0002440068,0.0001440926,0.0003835869,0.0002256285,0.0002381691,0.0001628021,0.0007144733,0.000002857073],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001043874,"about_ca_system_score_gemma":0.00002144082,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008160468,"about_ca_topic_score_gemma":0.000005646276,"domain_scores_codex":[0.9978547,0.0001600514,0.000647373,0.0004507243,0.0004907247,0.000396393],"domain_scores_gemma":[0.9984151,0.0002521646,0.0005910583,0.0004690512,0.0001030522,0.0001695895],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006328208,0.0001650147,0.0007450979,0.000172116,0.0001688793,0.00006480086,0.003770092,0.000003793027,0.9929232,0.00001734611,0.000009624362,0.001327218],"study_design_scores_gemma":[0.001607508,0.0001566929,0.001342711,0.0004971751,0.0002900121,0.0003859306,0.001826733,0.00007850322,0.9933329,0.0001524958,0.00007325244,0.0002561302],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984407,0.0004223819,0.0001664937,0.0001578039,0.00003748881,0.0001821241,0.00003037819,0.00002782701,0.0005347556],"genre_scores_gemma":[0.999273,0.0002038357,0.0001417074,0.00005597172,0.0001446614,0.00001717341,0.00007310952,0.0000552392,0.00003530617],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00194336,"threshold_uncertainty_score":0.9950308,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009149115244720408,"score_gpt":0.2025522078806838,"score_spread":0.1934030926359634,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}