{"id":"W2005139687","doi":"10.1021/ja002205d","title":"Self-Assembly of Organometallic Block Copolymers:  The Role of Crystallinity of the Core-Forming Polyferrocene Block in the Micellar Morphologies Formed by Poly(ferrocenylsilane-<i>b</i>-dimethylsiloxane) in <i>n</i>-Alkane Solvents","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":365,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts; Government of Ontario","keywords":"Micelle; Copolymer; Crystallinity; Chemistry; Polymer; Polymer chemistry; Crystallization; Chemical engineering; Amorphous solid; Morphology (biology); Core (optical fiber); Materials science; Crystallography; Organic chemistry; Composite material; Aqueous solution","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004609572,0.0002889277,0.0007514486,0.00002611346,0.0001016134,0.00001410936,0.001645851,0.0001404714,0.00006765348],"category_scores_gemma":[0.0001226971,0.0001470851,0.0006572061,0.0007952169,0.0006643842,0.0001117151,0.0001740177,0.0006918333,3.987989e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001252839,"about_ca_system_score_gemma":0.0001423789,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002177003,"about_ca_topic_score_gemma":0.00000633644,"domain_scores_codex":[0.9973851,0.000116972,0.001202815,0.0002016091,0.0006994166,0.0003940733],"domain_scores_gemma":[0.9965356,0.0005297941,0.002214165,0.000561345,0.0001008036,0.00005830703],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001672999,0.0005054381,0.008570444,0.00006956935,0.0001460082,7.423016e-7,0.002063693,0.00003067765,0.9863016,0.000001673239,0.00009914282,0.002043695],"study_design_scores_gemma":[0.0005946554,0.00005141089,0.001833665,0.0001432894,0.000148353,0.00004761088,0.00577822,0.0001445687,0.990398,0.00008122785,0.0006236496,0.0001553525],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963894,0.002549517,0.000004198755,0.0005868124,0.00003422745,0.0001287167,0.00006581406,0.000007284762,0.0002340131],"genre_scores_gemma":[0.9981627,0.001076789,0.0002529196,0.0003592162,0.0000652122,0.000005115879,0.000004507855,0.00002828283,0.00004521485],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006736779,"threshold_uncertainty_score":0.5997956,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007544089787443798,"score_gpt":0.2260029827334109,"score_spread":0.2184588929459671,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}