{"id":"W2005220529","doi":"10.1021/jo0006775","title":"Laser Flash Photolysis Evidence for Styryl Radical Cation Cyclization in the SET-Induced Photorearrangement of a <i>p</i>-Methoxy-Substituted 2-Phenylallyl Phosphite","year":2000,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Chemistry; Flash photolysis; Photochemistry; Reaction rate constant; Phosphonate; Trimethyl phosphite; Radical ion; Nucleophile; Triphenyl phosphite; Biphenyl; Ketyl; Substituent; Medicinal chemistry; Inorganic chemistry; Ion; Kinetics; Benzophenone; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001191388,0.0002254902,0.0003769062,0.00003084949,0.0001080531,0.00003230005,0.0008979645,0.0002067777,0.004355687],"category_scores_gemma":[0.001351977,0.0001490291,0.0002253126,0.0005322727,0.0001640084,0.0001745831,0.00003184779,0.0006282418,0.000007383925],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002859437,"about_ca_system_score_gemma":0.0002465836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000483862,"about_ca_topic_score_gemma":0.00001482457,"domain_scores_codex":[0.9977584,0.00007231099,0.0009493509,0.0002055535,0.0007330012,0.0002813068],"domain_scores_gemma":[0.9972065,0.001288356,0.0006134931,0.0005596773,0.0002085283,0.0001234407],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003951447,0.0002278654,0.00011265,0.0001328302,0.00009438299,0.000004950781,0.0008366865,0.00006712476,0.9954624,9.13703e-7,0.0005990967,0.002065958],"study_design_scores_gemma":[0.001252946,0.00002582413,0.0001708501,0.0003275738,0.0002961835,0.0001136809,0.0004287969,0.0005718271,0.9951183,0.0001535291,0.001385178,0.0001553326],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973326,0.0003709335,0.0004300888,0.0007512408,0.00003988458,0.0002455072,0.00001813811,0.00001637669,0.0007952334],"genre_scores_gemma":[0.9984651,0.0004384007,0.0003891218,0.0001357256,0.0002563195,0.0000325583,0.00002190946,0.00003079983,0.0002301275],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004348303,"threshold_uncertainty_score":0.9965545,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03684079130915138,"score_gpt":0.3017248627656273,"score_spread":0.2648840714564759,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}