{"id":"W2005254092","doi":"10.1021/ja000752t","title":"Synthesis and Electronic Structure Investigations of α,ω-Bis(arylthio)oligothiophenes:  Toward Understanding Wire-Linker Interactions in Molecular-Scale Electronic Materials","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":96,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Thiophene; Stille reaction; Cyclic voltammetry; Alkyl; Conjugated system; Oligomer; Bathochromic shift; Photochemistry; Molecular wire; Polymer chemistry; Crystallography; Organic chemistry; Molecule; Polymer; Electrochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002436141,0.0001280959,0.000340217,0.00002726403,0.00009595357,0.000041705,0.00030462,0.00003987327,0.0002710358],"category_scores_gemma":[0.00006094626,0.00009558217,0.000164627,0.0003668391,0.0004834735,0.0001201766,0.00005285304,0.0003315494,8.511761e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003449857,"about_ca_system_score_gemma":0.0002326687,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001559226,"about_ca_topic_score_gemma":0.00001581312,"domain_scores_codex":[0.9987862,0.0000841947,0.0004594828,0.000164083,0.0002026821,0.0003034004],"domain_scores_gemma":[0.9990218,0.0001640803,0.0005188768,0.00018662,0.0000393605,0.00006924893],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001891134,0.00003284342,0.0002224539,0.00001217215,0.0000302916,1.803728e-7,0.0005992998,0.00004783147,0.998319,0.0003137403,0.0001452308,0.0002580103],"study_design_scores_gemma":[0.0001417623,0.00002414798,0.0002835618,0.00006078059,0.00006603426,0.00004912999,0.001128489,0.00002271439,0.9930263,0.004855512,0.0002408615,0.0001006666],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960868,0.0001465525,0.0002148746,0.00336039,0.0000468943,0.00008616027,0.00002016302,0.000009012395,0.00002912028],"genre_scores_gemma":[0.9980512,0.000180195,0.001291837,0.0003696749,0.00006465379,0.000006442237,8.371981e-7,0.00001465842,0.00002050448],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005292695,"threshold_uncertainty_score":0.3897728,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01645525808563914,"score_gpt":0.262450043491927,"score_spread":0.2459947854062879,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}