{"id":"W2005377329","doi":"10.1021/ol100139t","title":"A Glass Forming Module for Organic Molecules: Making Tetraphenylporphyrin Lose its Crystallinity","year":2010,"lang":"en","type":"article","venue":"Organic Letters","topic":"Liquid Crystal Research Advancements","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Royal Military College of Canada","funders":"","keywords":"Tetraphenylporphyrin; Chemistry; Crystallinity; Surface modification; Molecule; Organic molecules; Rational design; Polymer chemistry; Combinatorial chemistry; Chemical engineering; Organic chemistry; Nanotechnology; Crystallography; Materials science; Porphyrin; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007676622,0.0003212066,0.0003057581,0.0001426298,0.0003442193,0.0002419423,0.000883805,0.000114547,0.002414323],"category_scores_gemma":[0.00103217,0.0003094395,0.0001164147,0.0003701341,0.0001449502,0.0007752288,0.0003465994,0.0004023997,0.0003714213],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001995072,"about_ca_system_score_gemma":0.0001728322,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007668692,"about_ca_topic_score_gemma":0.00008709907,"domain_scores_codex":[0.9970123,0.00006287073,0.0004512279,0.000697152,0.0006852809,0.001091178],"domain_scores_gemma":[0.9985079,0.0001993554,0.0002024137,0.0006690383,0.0001761111,0.0002452048],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006907936,0.00008257094,0.0001080531,0.0001038451,0.00001851172,0.00003206053,0.0001674481,0.000009337223,0.9981378,0.0003342138,0.0006686368,0.0002684408],"study_design_scores_gemma":[0.001096441,0.0001234571,0.0001572984,0.00004372746,0.00002006033,0.00002787862,0.00007012396,0.0004821502,0.993702,0.0005760404,0.003302615,0.0003982037],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9377829,0.00002721708,0.05897074,0.001321135,0.0007264052,0.0008235761,0.0000644928,0.0001892547,0.00009426787],"genre_scores_gemma":[0.9832922,0.000005209109,0.01428045,0.001770329,0.0003062977,0.00009954006,0.00001701433,0.0001082441,0.0001206766],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04550933,"threshold_uncertainty_score":0.9999357,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02014038629746207,"score_gpt":0.2847351059150593,"score_spread":0.2645947196175973,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}