{"id":"W2005546856","doi":"10.1007/s11244-009-9320-3","title":"Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on Cu/SiO2","year":2009,"lang":"en","type":"article","venue":"Topics in Catalysis","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":39,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"","keywords":"Formate; Methanol; Catalysis; Chemistry; Water-gas shift reaction; Methyl formate; Inorganic chemistry; Decomposition; Steady state (chemistry); Carbon monoxide; Analytical Chemistry (journal); Photochemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001042367,0.0002288305,0.0006043864,0.0001757875,0.0001430134,0.00005727491,0.0006148804,0.00009840234,0.0001827308],"category_scores_gemma":[0.002061451,0.000201229,0.00009279279,0.000607099,0.0003408698,0.0004005772,0.000153351,0.000117167,0.0001122037],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000234133,"about_ca_system_score_gemma":0.00008349225,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001727848,"about_ca_topic_score_gemma":0.0001637943,"domain_scores_codex":[0.9979412,0.0001032433,0.0005709514,0.0004809777,0.0005122166,0.0003913998],"domain_scores_gemma":[0.9973792,0.001299671,0.0003054093,0.0007698816,0.0001776905,0.00006814705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004455782,0.0002482248,0.00006908644,0.0000974377,0.00002438936,0.00002292625,0.001014243,0.01483281,0.9809498,0.001546574,0.0000680816,0.001081844],"study_design_scores_gemma":[0.0001578692,0.00007902116,0.001033985,0.0001065773,0.0000797551,0.00001023569,0.0004837281,0.0004811202,0.9860689,0.01112794,0.0001226473,0.0002482357],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970217,0.0001372162,0.0002088699,0.0008001712,0.0003301842,0.0001818067,0.0001055893,0.00007689719,0.001137596],"genre_scores_gemma":[0.9980615,0.0001192468,0.001361287,0.0001697039,0.00004856927,0.00001636488,0.00001109945,0.00001027965,0.0002019827],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01435169,"threshold_uncertainty_score":0.8205882,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03705830930427843,"score_gpt":0.3373845921090851,"score_spread":0.3003262828048067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}