{"id":"W2005880794","doi":"10.1007/s10751-006-9291-8","title":"Search for the stannous ion in a chloride/fluoride matrix: cases of Ba1−x Sn x Cl1+y F1−y and of Ba2SnCl6","year":2006,"lang":"en","type":"article","venue":"Hyperfine Interactions","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"Concordia University","funders":"","keywords":"Tin; Ionic bonding; Lone pair; Chemistry; Crystallography; Ionic compound; Covalent bond; Valence (chemistry); Ion; Inorganic chemistry; SN2 reaction; Divalent; Octahedron; Quadrupole splitting; Anhydrous; Mössbauer spectroscopy; Stereochemistry; Crystal structure; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003299718,0.0002869788,0.0003485576,0.001092933,0.001279527,0.0007033036,0.0009691645,0.001325638,0.003160617],"category_scores_gemma":[0.0007065931,0.0002733878,0.0002411675,0.0004832452,0.0008032022,0.0005032773,0.0005374705,0.0002267271,0.0002355072],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003910761,"about_ca_system_score_gemma":0.000410651,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005729817,"about_ca_topic_score_gemma":0.006427091,"domain_scores_codex":[0.9998724,0.00001914253,0.000005758385,0.00003210728,0.00003207949,0.00003844509],"domain_scores_gemma":[0.9997672,0.00007506255,0.0000582563,0.00003233247,0.0000365169,0.00003059796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004635129,0.0001680867,0.03107024,0.0005288853,0.0001251897,0.01057769,0.001756179,0.006346371,0.9009451,0.02821773,0.002334353,0.01329508],"study_design_scores_gemma":[0.0006337839,0.001252721,0.02279588,0.00008246073,0.0002463382,0.012104,0.004780873,0.07649072,0.8492545,0.01530848,0.01693629,0.0001140208],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922853,0.0002915314,0.001010088,0.0003854216,0.000008109781,0.0000115752,0.00006947928,0.00005656998,0.005881913],"genre_scores_gemma":[0.9977677,0.0000630203,0.001251115,0.00002297911,0.00000392419,0.000004395849,0.00005749676,0.000006042374,0.0008232949],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005729817,"threshold_uncertainty_score":0.01139295,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01539045633432076,"score_gpt":0.2720738659474883,"score_spread":0.2566834096131676,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}