{"id":"W2006574686","doi":"10.1021/ol049527x","title":"Distinguishing between Abstraction and Addition as the First Step in the Reaction of a Nitroxyl Radical with Cyclohexene","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Nitroxyl; Cyclohexene; Abstraction; Organic chemistry; Photochemistry; Computational chemistry; Catalysis; Epistemology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005117106,0.0003879904,0.0001761,0.0002113067,0.0002514027,0.0003060315,0.0003904387,0.00033714,0.001247772],"category_scores_gemma":[0.0005119282,0.0002278659,0.0001696403,0.00008218136,0.0004772902,0.0004027789,0.0003093171,0.001097301,0.0002421816],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001935702,"about_ca_system_score_gemma":0.0003044612,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001660586,"about_ca_topic_score_gemma":0.0004869027,"domain_scores_codex":[0.9998185,0.00003661502,0.000009014753,0.00004388902,0.00005199856,0.00004002701],"domain_scores_gemma":[0.9995708,0.0001745483,0.0001059691,0.00007605818,0.0000287589,0.00004390159],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002710221,0.00002250662,0.0004381264,0.00008018873,0.000009328265,0.00008754479,0.00008365796,0.00007097988,0.9931921,0.001058609,0.00003702506,0.004648835],"study_design_scores_gemma":[0.00001052538,0.0001253531,0.000490005,0.000003201033,0.0000062073,0.00009982568,0.00001407337,0.0002335785,0.998418,0.0001342944,0.0004587392,0.000006371785],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9289905,0.001541297,0.06476755,0.0002593036,0.0001341753,0.0001382904,0.0001738564,0.0001757368,0.003819161],"genre_scores_gemma":[0.9804291,0.0007632326,0.01672905,0.00003986329,0.00001830817,0.00004879567,0.00008357039,0.00001796199,0.001869996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001247772,"threshold_uncertainty_score":0.004174173,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007173434479512884,"score_gpt":0.2136603582669839,"score_spread":0.206486923787471,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}