{"id":"W2006803633","doi":"10.1139/v09-020","title":"Activation of the <i>N</i> C–H bond of Morita–Baylis–Hillman adducts of <i>N</i> -substituted isatins with cerium ammonium nitrate (CAN) and alcohol (ROH)","year":2009,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Biological Activity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Council of Scientific and Industrial Research, India","keywords":"Chemistry; Isatin; Adduct; Medicinal chemistry; Baylis–Hillman reaction; Cerium; Ammonium nitrate; Reactivity (psychology); Alcohol; Organic chemistry; Propargyl alcohol; Aryl; Propargyl; Ammonium; Stereochemistry; Catalysis; Alkyl","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001928454,0.0002369021,0.0001170467,0.00009896569,0.0001463101,0.00005226448,0.0002190869,0.0002450517,0.001533053],"category_scores_gemma":[0.0001726,0.00009488159,0.0002020662,0.00009454317,0.0001637499,0.0001749634,0.0001207118,0.0002829671,0.0002020464],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001603686,"about_ca_system_score_gemma":0.0001539591,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009968731,"about_ca_topic_score_gemma":0.001692834,"domain_scores_codex":[0.9999083,0.00001863172,0.000003636185,0.00001590796,0.00002133053,0.00003213793],"domain_scores_gemma":[0.9998735,0.00002574407,0.00003841599,0.00001719658,0.00002913685,0.00001603924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001109598,0.00001870808,0.0002790625,0.0000698116,0.000008960641,0.00007698605,0.00006620234,0.0001499769,0.9973822,0.0001344625,0.00003703948,0.001665759],"study_design_scores_gemma":[0.000004179922,0.0003133891,0.001387784,0.000003255373,0.00000637534,0.0001079385,0.00002304245,0.0002005832,0.9970392,0.00002648757,0.0008840006,0.000003747365],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918334,0.0007077371,0.002567231,0.00006106103,0.00001386725,0.00003333301,0.00007514949,0.00001908408,0.004689157],"genre_scores_gemma":[0.9960685,0.0003888943,0.001240209,0.00003574241,0.000003101292,0.00001055961,0.0001268505,0.000007675245,0.002118501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001533053,"threshold_uncertainty_score":0.005128622,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008903958509289824,"score_gpt":0.1915642200959373,"score_spread":0.1826602615866475,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}