{"id":"W2006803633","doi":"10.1139/v09-020","title":"Activation of the <i>N</i> C–H bond of Morita–Baylis–Hillman adducts of <i>N</i> -substituted isatins with cerium ammonium nitrate (CAN) and alcohol (ROH)","year":2009,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Biological Activity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Council of Scientific and Industrial Research, India","keywords":"Chemistry; Isatin; Adduct; Medicinal chemistry; Baylis–Hillman reaction; Cerium; Ammonium nitrate; Reactivity (psychology); Alcohol; Organic chemistry; Propargyl alcohol; Aryl; Propargyl; Ammonium; Stereochemistry; Catalysis; Alkyl","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001443088,0.0001316515,0.0002666213,0.00002307258,0.0000434205,0.000007921094,0.0002181728,0.0001498111,0.00001333005],"category_scores_gemma":[0.0001305944,0.00008571819,0.00009737823,0.0001043171,0.0002877527,0.000009081622,0.00001433309,0.0001359983,3.622161e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001931002,"about_ca_system_score_gemma":0.0004735107,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003280475,"about_ca_topic_score_gemma":0.0003486609,"domain_scores_codex":[0.9992197,0.00002768367,0.0003266277,0.0001355677,0.0001272022,0.000163227],"domain_scores_gemma":[0.998795,0.00001886422,0.0005391737,0.0002109926,0.0002630797,0.000172936],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001304355,0.00004051994,0.006922842,0.00004215797,0.00005189655,0.000002633515,0.00003981614,0.00001401252,0.9916376,0.000008249946,0.0002587796,0.0008510428],"study_design_scores_gemma":[0.0003951881,0.0001840061,0.0215224,0.00009555426,0.0000268129,0.00005576754,0.0001258601,0.00000153303,0.9767639,0.00006611976,0.0006649463,0.00009788376],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977347,0.0002765885,0.00001418639,0.0004941114,0.00003012994,0.0000710336,0.00007493238,8.711409e-7,0.001303485],"genre_scores_gemma":[0.999539,0.00004353536,0.0001590042,0.000113533,0.00009543695,7.794716e-7,0.000009675455,0.000006496788,0.00003254182],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01487369,"threshold_uncertainty_score":0.3495487,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008903958509289824,"score_gpt":0.1915642200959373,"score_spread":0.1826602615866475,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}