{"id":"W2007273287","doi":"10.1016/j.molstruc.2006.02.021","title":"Isomerisation: Don't forget the possibility of enhanced tunnelling! A simple two-state model for the on-resonance and near-resonance behaviour of enhanced tunnelling","year":2006,"lang":"en","type":"article","venue":"Journal of Molecular Structure","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada; National Institute of Advanced Industrial Science and Technology","keywords":"Chemistry; Quantum tunnelling; Resonance (particle physics); Simple (philosophy); Isomerization; Quantum mechanics; Physics; Epistemology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001423191,0.000230351,0.000434267,0.0000202879,0.0001879441,0.00002428475,0.0002942971,0.00003811104,0.000004796013],"category_scores_gemma":[0.00002520438,0.0001424635,0.0002602155,0.0001426937,0.0002515387,0.00009927178,0.00005628003,0.0003175834,5.993322e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002360721,"about_ca_system_score_gemma":0.00006345786,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003830773,"about_ca_topic_score_gemma":0.000009607291,"domain_scores_codex":[0.9985608,0.00003247571,0.0006230004,0.00022112,0.0003184462,0.0002441282],"domain_scores_gemma":[0.9981112,0.0002492048,0.0008786555,0.0003114259,0.0004098802,0.00003965856],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002981597,0.00008637724,0.0009907172,0.00004025564,0.0001132283,7.106098e-7,0.001015168,0.4524265,0.5338065,0.001847522,0.00005656561,0.009318231],"study_design_scores_gemma":[0.0009944942,0.00009181742,0.001529507,0.00005792873,0.00009018277,9.439883e-7,0.0001940777,0.01568901,0.7166084,0.2645576,0.00004071513,0.0001453448],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7067839,0.0009670507,0.291677,0.00009196149,0.00004340926,0.0002293408,0.0001790898,0.00000262309,0.00002568675],"genre_scores_gemma":[0.9940089,0.00002263945,0.005709004,0.00004379742,0.0001456183,0.00001083452,0.000007665132,0.00002500822,0.00002650575],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4367375,"threshold_uncertainty_score":0.5809491,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007425695535845396,"score_gpt":0.2545748490465473,"score_spread":0.2471491535107019,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}