{"id":"W2007279763","doi":"10.1063/1.2733643","title":"Electronic anisotropy between open shell atoms in first and second order perturbation theory","year":2007,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Quantum Electrodynamics and Casimir Effect","field":"Physics and Astronomy","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy; Office of Science; Basic Energy Sciences; University of Montana; National Science Foundation","keywords":"Multipole expansion; Anisotropy; Perturbation theory (quantum mechanics); van der Waals force; Adiabatic process; Physics; Tensor (intrinsic definition); Quantum mechanics; Linear molecular geometry; Open shell; Atomic physics; Chemistry; Classical mechanics; Molecule; Mathematics; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001103021,0.0001315681,0.0002456908,0.00002360493,0.00005673282,0.00004528135,0.0003460791,0.00003739193,0.00006245335],"category_scores_gemma":[0.000009705213,0.00008967568,0.00006263344,0.0001820897,0.00006497097,0.0001857485,0.00008546124,0.0004897509,0.00000272526],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006413382,"about_ca_system_score_gemma":0.0000681622,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001083213,"about_ca_topic_score_gemma":0.000003355107,"domain_scores_codex":[0.9991049,0.00006720693,0.0002962495,0.00009435006,0.0001401337,0.0002971912],"domain_scores_gemma":[0.9990263,0.0004871454,0.0002243293,0.0001292957,0.00007010833,0.0000628507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.001361473,0.0006808896,0.02824641,0.00005957592,0.0005728073,0.000008449475,0.002050952,0.0001151083,0.1307679,0.7743131,0.0006702688,0.06115311],"study_design_scores_gemma":[0.00127946,0.0002597478,0.002251166,0.00003751831,0.0000905425,0.000009988728,0.0001224924,0.0007273972,0.06057505,0.9337422,0.0007119374,0.0001924924],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":"theoretical_or_conceptual","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.984525,0.0001276235,0.01321202,0.0001581331,0.00002309454,0.0001316648,0.000003738341,0.000002532359,0.001816198],"genre_scores_gemma":[0.9993095,0.00001101097,0.00007238361,0.00006392658,0.0004384702,0.000001083412,0.000006435248,0.00001704846,0.00008011186],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1594291,"threshold_uncertainty_score":0.3656868,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005793006690633001,"score_gpt":0.2462799371328178,"score_spread":0.2404869304421848,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}