{"id":"W2007291511","doi":"10.1021/jo901653d","title":"Simple Reaction Conditions for the Formation of Ketonitrones from Ketones and Hydroxylamines","year":2009,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Simple (philosophy); Chemistry; Philosophy; Epistemology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005199998,0.0001243651,0.0001953632,0.00001340166,0.0002014186,0.00000993305,0.0002860287,0.0001428857,0.0006010784],"category_scores_gemma":[0.0003052637,0.00007939213,0.00007357324,0.0000933694,0.0001550838,0.0001216858,0.00003268391,0.0004162542,0.000001570164],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005502713,"about_ca_system_score_gemma":0.00006474667,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004484431,"about_ca_topic_score_gemma":0.000001773067,"domain_scores_codex":[0.9991769,0.00004509872,0.0004440341,0.00007044363,0.0001243816,0.0001391544],"domain_scores_gemma":[0.9977486,0.001310788,0.0005371039,0.0001746363,0.0001705933,0.00005833032],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002124111,0.00007177844,0.0001666414,0.00003481906,0.00009920426,0.000001165969,0.0003792564,0.00002437242,0.9944124,0.000006157575,0.003426707,0.001165107],"study_design_scores_gemma":[0.0009883423,0.00005496499,0.001241852,0.00001754283,0.0004505169,0.000310488,0.0007925858,0.0005496973,0.9880632,0.00242825,0.005020736,0.00008186112],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99457,0.001328077,0.0002973969,0.003227346,0.0001820823,0.0001161729,0.0000544364,0.00001285879,0.0002116617],"genre_scores_gemma":[0.9981871,0.0007142251,0.00004498449,0.000193722,0.0006232568,0.00000197248,0.00002033502,0.00001067123,0.0002037454],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006349217,"threshold_uncertainty_score":0.6581386,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04643668226002477,"score_gpt":0.3739081922460517,"score_spread":0.3274715099860269,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}