{"id":"W2007344394","doi":"10.1021/om040051v","title":"Bridging Methylene to Bridging Acyl Conversion in Heterobinuclear Rh/Ru Complexes:  Models for Adjacent-Metal Involvement in Bimetallic Catalysts","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Methylene; Hydride; Agostic interaction; Protonation; Carbene; Migratory insertion; Bimetallic strip; Adduct; Metal; Ligand (biochemistry); Medicinal chemistry; Stereochemistry; Catalysis; Methyl group; Cyclopentadiene; Nuclear magnetic resonance spectroscopy; Organic chemistry; Group (periodic table)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001252674,0.0003211566,0.0003709638,0.0001541228,0.0002267507,0.0005508192,0.0009521001,0.0006125321,0.001716132],"category_scores_gemma":[0.0001876986,0.0002356071,0.0001703594,0.0001365403,0.0003153773,0.000457715,0.0003759653,0.0005384155,0.0004635177],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007174241,"about_ca_system_score_gemma":0.0001435489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008221579,"about_ca_topic_score_gemma":0.0009434907,"domain_scores_codex":[0.9999124,0.00001247354,0.000005273679,0.00002101558,0.00002298303,0.00002591091],"domain_scores_gemma":[0.9999565,0.00001011596,0.000008124544,0.000009627841,0.000003475685,0.00001223959],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005082709,0.0002478398,0.0005561598,0.0002226744,0.00002745868,0.0004162182,0.0002794846,0.007323688,0.9731813,0.01303576,0.0001854801,0.004015564],"study_design_scores_gemma":[0.0002139511,0.0009870518,0.001201072,0.00002041453,0.00004279997,0.0002497663,0.0001853834,0.08306886,0.9077691,0.002280609,0.003938131,0.00004286247],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946188,0.0002108312,0.002481024,0.00005654943,0.00001204902,0.00003492552,0.0000499973,0.00009519225,0.002440644],"genre_scores_gemma":[0.9975134,0.0001106982,0.00131491,0.00000997743,0.000002102301,0.00002586374,0.00005148541,0.00001843336,0.0009530482],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001716132,"threshold_uncertainty_score":0.00574106,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02715351450740625,"score_gpt":0.2431412204461608,"score_spread":0.2159877059387546,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}