{"id":"W2007571941","doi":"10.1021/om030116e","title":"Easy Making and Breaking of Metal−Metal Donor−Acceptor Bonds in the Chemistry of Binuclear Methylplatinum(II) Complexes","year":2003,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Metal; Acceptor; Ligand (biochemistry); Crystallography; Stereochemistry; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008632745,0.0004087976,0.0009556544,0.0001765229,0.0001659048,0.00005653285,0.0006909625,0.0001826675,0.02082121],"category_scores_gemma":[0.0004110758,0.0003336423,0.0002903611,0.001051426,0.000361421,0.0001857816,0.000266025,0.0003165515,0.000006504105],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005370943,"about_ca_system_score_gemma":0.00006925967,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005158752,"about_ca_topic_score_gemma":0.00002335488,"domain_scores_codex":[0.9974198,0.0001040716,0.000964465,0.000530371,0.0005501139,0.000431192],"domain_scores_gemma":[0.9979827,0.0003728003,0.0006000787,0.0008732071,0.00009217034,0.00007905597],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002136417,0.0003845333,0.003066407,0.000443897,0.0003665336,0.0000061175,0.001125847,0.00001691536,0.9849589,0.004875987,0.00001032976,0.004723208],"study_design_scores_gemma":[0.001353773,0.00008532032,0.006211144,0.0001524552,0.0009343129,0.0001386099,0.004980608,0.0002656406,0.9244823,0.001356707,0.05902583,0.001013232],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9490237,0.001359108,0.00005205282,0.00005932379,0.00002308901,0.0001026152,0.00007065929,0.0000321127,0.04927729],"genre_scores_gemma":[0.9969285,0.00008352513,0.001625412,0.0000347768,0.00004795074,0.00001346855,0.00002998646,0.00006736481,0.001169088],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06047649,"threshold_uncertainty_score":0.9999115,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01769730991484798,"score_gpt":0.2361884280573111,"score_spread":0.2184911181424631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}