{"id":"W2007653403","doi":"10.1016/j.jinorgbio.2007.01.003","title":"Cooperative influence of thiolate ligands on the bio-relevant coordination chemistry of bismuth","year":2007,"lang":"en","type":"article","venue":"Journal of Inorganic Biochemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":35,"is_retracted":false,"has_abstract":false,"ca_institutions":"Dalhousie University","funders":"Killam Trusts; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Nova Scotia Research Innovation Trust","keywords":"Bismuth; Chemistry; Electrospray ionization; Molecule; Cysteine; Mass spectrometry; Inorganic chemistry; Sulfur; Coordination complex; Combinatorial chemistry; Organic chemistry; Ion; Metal; Chromatography; Enzyme","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002032248,0.000201275,0.0002168802,0.0001167036,0.000225726,0.0003611353,0.0003813014,0.0002185569,0.001986757],"category_scores_gemma":[0.0004080854,0.0001352645,0.00008285161,0.00009067555,0.0003043578,0.0002084818,0.0003514495,0.0002355278,0.0002419097],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001719235,"about_ca_system_score_gemma":0.0001569861,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000340976,"about_ca_topic_score_gemma":0.0005846504,"domain_scores_codex":[0.9998847,0.00003656907,0.00000716862,0.00001886509,0.00002590553,0.00002675458],"domain_scores_gemma":[0.9998482,0.00007399677,0.0000208928,0.00001345632,0.00001846538,0.0000249703],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006309304,0.00002965664,0.0002095614,0.0001210675,0.00001377685,0.0001116814,0.000128879,0.0002807833,0.9934846,0.001082316,0.0001655219,0.003741334],"study_design_scores_gemma":[0.00003729221,0.0001942009,0.0008899395,0.000007651759,0.00001998703,0.0001172738,0.00007968436,0.002055907,0.9944213,0.0003538585,0.001810176,0.00001265695],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963289,0.0005317532,0.0007503018,0.00008535357,0.00002185519,0.000008222707,0.00001759091,0.00003038909,0.002225644],"genre_scores_gemma":[0.9991513,0.0001617721,0.0002322886,0.00002591402,0.000005524768,0.000003968469,0.00001854887,0.000008272987,0.0003923623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001986757,"threshold_uncertainty_score":0.006646335,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01664670822097206,"score_gpt":0.2509853782514052,"score_spread":0.2343386700304331,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}