{"id":"W2007698616","doi":"10.1021/ic9002274","title":"Ferromagnetic Coupling by Spin Polarization in a Trinuclear Copper(II) Metallacyclophane with a Triangular Cage-Like Structure","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"Centre National de la Recherche Scientifique","keywords":"Chemistry; Copper; Crystallography; Benzene; Ground state; Ferromagnetism; Density functional theory; Monoclinic crystal system; Stereochemistry; Molecular physics; Crystal structure; Condensed matter physics; Computational chemistry; Atomic physics; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001919105,0.0002849663,0.0003406339,0.00005641565,0.000151529,0.0001280005,0.0004390097,0.0001835625,0.005178778],"category_scores_gemma":[0.0001207011,0.0002762454,0.00003674806,0.000532678,0.00007890069,0.0001890133,0.00008261878,0.0002413005,0.00002347432],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001646934,"about_ca_system_score_gemma":0.0001238015,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000971352,"about_ca_topic_score_gemma":0.00003441227,"domain_scores_codex":[0.998172,0.00003005887,0.0004182571,0.0005536731,0.0004289288,0.0003970138],"domain_scores_gemma":[0.9991217,0.00003794015,0.0001845047,0.0004477972,0.00008511978,0.0001229917],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006838574,0.00008299432,0.0001488445,0.00004345206,0.000004447951,0.00002312531,0.0001683756,0.0002616385,0.9982292,0.00001906418,0.000725748,0.0002246932],"study_design_scores_gemma":[0.002333611,0.0002538874,0.002734725,0.00006201692,0.00003712574,0.0001102106,0.0001165243,0.002207176,0.989575,0.0002434969,0.001843916,0.0004823066],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9975997,0.00057815,0.0001233611,0.0006278735,0.00009127501,0.0002656191,0.0000499786,0.0001531805,0.0005109129],"genre_scores_gemma":[0.996684,0.000008739011,0.001210766,0.0002162611,0.00008539273,0.000006442897,0.0000767957,0.00003441419,0.001677237],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008654227,"threshold_uncertainty_score":0.9999689,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004817831525611405,"score_gpt":0.2129231490840206,"score_spread":0.2081053175584092,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}