{"id":"W2007753850","doi":"10.1021/ja808390a","title":"Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":97,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; NMR spectra database; Metallocene; Crystallography; Nuclear magnetic resonance spectroscopy; Electric field gradient; Computational chemistry; Molecule; Spectral line; Physical chemistry; Stereochemistry; Organic chemistry; Polymerization; Electric field","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001013283,0.0001331485,0.0003988855,0.00001106265,0.00006261762,0.000008750235,0.0003994069,0.00003596336,0.00007828174],"category_scores_gemma":[0.00001949308,0.00009202315,0.000624449,0.0003092093,0.0003320021,0.00008394538,0.0000361386,0.0003485817,6.714679e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008868636,"about_ca_system_score_gemma":0.00002165461,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006687496,"about_ca_topic_score_gemma":1.662431e-7,"domain_scores_codex":[0.9989733,0.000009422427,0.0004583415,0.0001176438,0.0002659912,0.0001753337],"domain_scores_gemma":[0.9987712,0.00004959349,0.0007714328,0.0002283884,0.0001020141,0.00007740706],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003395101,0.0001771448,0.00002871705,0.00001403048,0.00006949956,4.867371e-7,0.0001494118,0.0000879328,0.9962762,0.00008770666,0.0003409005,0.002734006],"study_design_scores_gemma":[0.0002900492,0.00006653847,0.0003327479,0.00003250323,0.00008693244,0.00004604841,0.0002335012,0.0002668888,0.9920821,0.004603246,0.001841104,0.0001183022],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9904734,0.00006061361,0.007519578,0.001664799,0.000006149057,0.0000412222,0.00002333105,0.00002762252,0.0001832706],"genre_scores_gemma":[0.9867485,0.0002003386,0.01234581,0.0004923219,0.000144445,0.000002360563,0.000004847892,0.00001327735,0.00004810971],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004826234,"threshold_uncertainty_score":0.3752595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01163091384931235,"score_gpt":0.2893913104669084,"score_spread":0.2777603966175961,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}