{"id":"W2007839411","doi":"10.1021/ja0725652","title":"Enhancing Electron Accepting Ability of Triarylboron via π-Conjugation with 2,2‘-Bipy and Metal Chelation:  5,5‘-Bis(BMes<sub>2</sub>)-2,2‘-bipy and Its Metal Complexes","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":169,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ligand (biochemistry); Chelation; Metal; Fluoride; Metal ions in aqueous solution; Adduct; Inorganic chemistry; Medicinal chemistry; Lewis acids and bases; One-electron reduction; Stereochemistry; Crystallography; Electrochemistry; Organic chemistry; Physical chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001140691,0.0003347643,0.0002336795,0.0001432783,0.000120433,0.0002454008,0.000320174,0.000354428,0.001148382],"category_scores_gemma":[0.0001203627,0.0001633024,0.0001168128,0.0001624463,0.0001402649,0.0002219387,0.0003320723,0.0002520615,0.0003309226],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002152369,"about_ca_system_score_gemma":0.0001259327,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004222929,"about_ca_topic_score_gemma":0.0008893319,"domain_scores_codex":[0.9999038,0.00001852191,0.000006615816,0.00001717191,0.00001926698,0.0000345026],"domain_scores_gemma":[0.9999583,0.000005950589,0.00001167378,0.000003297243,0.000006800142,0.00001402586],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007872492,0.00001708764,0.0000588174,0.00008435269,0.000004704299,0.00002559622,0.00001863321,0.00008112329,0.9981239,0.0001528167,0.0000402874,0.001313687],"study_design_scores_gemma":[0.00001848919,0.0003043946,0.0005390056,0.000005809586,0.0000102265,0.00007164026,0.00001214342,0.0005272026,0.9969172,0.0000289047,0.001555523,0.000009325433],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940616,0.001301263,0.00246798,0.00008082394,0.00002132225,0.00001935368,0.00007891251,0.0000787656,0.001889839],"genre_scores_gemma":[0.9947357,0.0005904287,0.002884877,0.0000597603,0.000004513886,0.00002120317,0.0001182109,0.00001558061,0.001569843],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001148382,"threshold_uncertainty_score":0.003841698,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006885446608949448,"score_gpt":0.2394627801532048,"score_spread":0.2325773335442554,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}