{"id":"W2007861490","doi":"10.1002/chin.200948105","title":"ChemInform Abstract: Functionalization of Csp<sup>3</sup>—H Bond—Sc(OTf)<sub>3</sub>‐Catalyzed Domino 1,5‐Hydride Shift/Cyclization/Friedel—Crafts Acylation Reaction of Benzylidene Meldrum′s Acids.","year":2009,"lang":"en","type":"article","venue":"ChemInform","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Chemistry; Friedel–Crafts reaction; Domino; Hydride; Catalysis; Acylation; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Hydrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001251896,0.0006403536,0.0002319689,0.0002179272,0.0002220441,0.000151067,0.0003790297,0.0002895013,0.01033693],"category_scores_gemma":[0.0001406638,0.00009969236,0.000212693,0.0003343602,0.0001609107,0.0003489937,0.0001993097,0.0004074274,0.002532167],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003588432,"about_ca_system_score_gemma":0.0005454778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001616735,"about_ca_topic_score_gemma":0.002137781,"domain_scores_codex":[0.9999274,0.000006930386,0.000003251331,0.00001311284,0.00001691357,0.00003238002],"domain_scores_gemma":[0.9999632,0.000005519374,0.000009031081,0.000004431234,0.00000688206,0.00001096554],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009756167,0.0001020639,0.0001763911,0.0006054167,0.00003173927,0.000387156,0.00009525671,0.0007075399,0.9579094,0.001983079,0.005488938,0.03153729],"study_design_scores_gemma":[0.0000459488,0.0002845395,0.000649338,0.00001038305,0.0000150717,0.0001898428,0.00001210426,0.000363461,0.9859434,0.0001269392,0.01234826,0.00001070943],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8835955,0.006776835,0.02590925,0.0009044254,0.0004914934,0.000233205,0.006861699,0.001151998,0.07407567],"genre_scores_gemma":[0.974962,0.002584646,0.003594421,0.0001730707,0.00004232076,0.00004010105,0.002538576,0.0001155041,0.01594939],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01033693,"threshold_uncertainty_score":0.03458047,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03225095528211709,"score_gpt":0.3215397565472225,"score_spread":0.2892888012651054,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}