{"id":"W2007906447","doi":"10.1021/ja010060k","title":"Minimizing Tocopherol-Mediated Radical Phase Transfer in Low-Density Lipoprotein Oxidation with an Amphiphilic Unsymmetrical Azo Initiator","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Mount Allison University","funders":"National Heart, Lung, and Blood Institute; National Institutes of Health","keywords":"Chemistry; Tocopherol; Amphiphile; Phase (matter); Low-density lipoprotein; Photochemistry; Polymer chemistry; Organic chemistry; Cholesterol; Biochemistry; Antioxidant; Vitamin E; Polymer; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002964324,0.0003149342,0.0001747403,0.0001256566,0.0001189268,0.0002143814,0.0001808183,0.0002584838,0.0003699102],"category_scores_gemma":[0.0003033596,0.000129697,0.0001721741,0.0001033359,0.0001659125,0.0002388961,0.0002166273,0.0003239657,0.0001922024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001573488,"about_ca_system_score_gemma":0.0001719871,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00023766,"about_ca_topic_score_gemma":0.0003112543,"domain_scores_codex":[0.9998425,0.00005035296,0.00001441753,0.00002836244,0.00003882009,0.00002540497],"domain_scores_gemma":[0.999782,0.0000659145,0.00008549589,0.00001861524,0.00002522342,0.00002278479],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006491751,0.00001737214,0.00005062652,0.00002027908,0.000002315523,0.00001275504,0.000009480308,0.00004561558,0.999145,0.00002710331,0.000003952331,0.0006006271],"study_design_scores_gemma":[0.000007282875,0.0001951179,0.0001803558,0.000001609156,0.000005545176,0.00002524569,0.00000286193,0.0003218334,0.9989657,0.000009345985,0.0002831046,0.000001885108],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959996,0.0007587404,0.002764193,0.00002277821,0.00001097605,0.00002307539,0.00002014503,0.00001971986,0.0003807911],"genre_scores_gemma":[0.9904366,0.0005999432,0.007956787,0.00001751041,0.000009265165,0.0000337381,0.0000576681,0.00001318404,0.0008753809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0003699102,"threshold_uncertainty_score":0.001567662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01277022790129346,"score_gpt":0.253494648732445,"score_spread":0.2407244208311516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}