{"id":"W2008009468","doi":"10.1021/om900571k","title":"A Spirocyclic, Bimetallic, Carbon-Bridged Bis(iminophosphorano)methanediide Complex of Palladium(II): Synthesis, Crystal Structure, Solution Behavior, and DFT Bonding Analysis","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Toluene; Palladium; Crystallography; Cis–trans isomerism; Nuclear magnetic resonance spectroscopy; Crystal structure; Benzene; NMR spectra database; Bimetallic strip; Stereochemistry; Structural isomer; Dilithium; Spectral line; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004836026,0.0001836101,0.0001781744,0.0001455953,0.0001213711,0.0002366395,0.0003544076,0.0002542941,0.0008344261],"category_scores_gemma":[0.0001030137,0.0001820532,0.00006831204,0.0001696883,0.0001617696,0.0001294684,0.0001396694,0.000216094,0.0001761512],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003862384,"about_ca_system_score_gemma":0.0001928024,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008512398,"about_ca_topic_score_gemma":0.001355357,"domain_scores_codex":[0.9999288,0.00000756271,0.000003842821,0.0000197867,0.00002599051,0.00001402309],"domain_scores_gemma":[0.9999686,0.000002724489,0.000007790401,0.000004095337,0.000004127323,0.00001265568],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001176324,0.0000264466,0.0002721227,0.00004220939,0.000007525695,0.00006649467,0.00002378929,0.00033899,0.9975888,0.0002067385,0.00008729814,0.001222149],"study_design_scores_gemma":[0.00002975361,0.0002004558,0.001377884,0.000002003794,0.000008569033,0.0001550247,0.00001730791,0.00155383,0.9948044,0.000041678,0.001802674,0.000006356121],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961556,0.0002158931,0.001779363,0.00004328379,0.000006301115,0.00001264201,0.0001459181,0.00007481464,0.001566156],"genre_scores_gemma":[0.9969619,0.0000907595,0.001464938,0.00001593024,0.000001542739,0.000008516489,0.0002406775,0.000009388306,0.001206377],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008512398,"threshold_uncertainty_score":0.002802372,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01781949959475219,"score_gpt":0.2365714805994027,"score_spread":0.2187519810046505,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}