{"id":"W2008110514","doi":"10.1002/cjce.5450820314","title":"A Hydration Shell‐Based Thermodynamic Model for Aqueous Two‐Phase Systems","year":2004,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Chemical and Physical Properties in Aqueous Solutions","field":"Chemical Engineering","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"People's Armed Police Force; Conselho Nacional de Desenvolvimento Científico e Tecnológico; Fundação de Amparo à Pesquisa do Estado de São Paulo","keywords":"Solvation shell; Aqueous solution; Solvation; Molecule; Ethylene glycol; Polymer; Thermodynamics; Chemistry; Phase (matter); Shell (structure); Work (physics); Materials science; Physical chemistry; Organic chemistry; Physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001760282,0.0002140929,0.0002914646,0.00008131929,0.0001333416,0.00008705448,0.0004277437,0.000119701,0.000007799738],"category_scores_gemma":[0.0003006942,0.0001591499,0.0002371187,0.0001624572,0.0001103338,0.000101159,0.00001424292,0.0005166247,0.000004782035],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007276473,"about_ca_system_score_gemma":0.0005628064,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008206916,"about_ca_topic_score_gemma":0.00005867985,"domain_scores_codex":[0.9987302,0.000007253786,0.000463896,0.0001397334,0.0002014648,0.000457463],"domain_scores_gemma":[0.9988818,0.0001482186,0.0001087675,0.000223576,0.0001598653,0.0004778093],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00002029939,0.00001967751,1.822866e-7,0.00003842311,0.00002585119,0.000004169538,0.0001071273,0.6023321,0.3931845,0.004098486,0.00003258492,0.0001366441],"study_design_scores_gemma":[0.00133825,0.00003352024,6.344544e-8,0.0001363595,0.00004977138,0.00004424913,0.000003551532,0.8842576,0.1116014,0.002179067,0.0001674814,0.0001886185],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.4919491,0.0006901756,0.5053763,0.0009957697,0.0003498671,0.0003179734,0.00005997832,0.00007265011,0.0001882387],"genre_scores_gemma":[0.9975892,5.906766e-7,0.001753555,0.0001003798,0.0004334526,0.00002636839,0.00001276132,0.00005192843,0.00003180069],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5056401,"threshold_uncertainty_score":0.6489945,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01615968737057568,"score_gpt":0.2216554241450316,"score_spread":0.2054957367744559,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}