{"id":"W2008126509","doi":"10.1016/j.jelechem.2014.08.032","title":"Experimental design methodology applied to electrochemical oxidation of carbamazepine using Ti/PbO2 and Ti/BDD electrodes","year":2014,"lang":"en","type":"article","venue":"Journal of Electroanalytical Chemistry","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":130,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre de Recherche Industrielle du Québec; Institut National de la Recherche Scientifique","funders":"","keywords":"Chemistry; Electrolysis; Anode; Electrochemistry; Carbamazepine; Factorial experiment; Aqueous solution; Central composite design; Electrolyte; Supporting electrolyte; Electrode; Continuous reactor; Bulk electrolysis; Nuclear chemistry; Chromatography; Response surface methodology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.005206354,0.002735569,0.002731618,0.001034007,0.001236352,0.001065326,0.002086919,0.002017242,0.006655958],"category_scores_gemma":[0.003702332,0.001414661,0.001815133,0.001452678,0.000889248,0.0003338391,0.0009187007,0.002234286,0.001160897],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00100265,"about_ca_system_score_gemma":0.002779533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001823214,"about_ca_topic_score_gemma":0.002420796,"domain_scores_codex":[0.9939791,0.001601594,0.0008017233,0.001132682,0.001900042,0.000584947],"domain_scores_gemma":[0.9968811,0.0009952959,0.0004683098,0.000343747,0.001181154,0.0001303602],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.005841387,0.005352146,0.001964372,0.006103923,0.0002882602,0.0002948173,0.0006068187,0.006964569,0.9113022,0.001710013,0.0006918907,0.05887963],"study_design_scores_gemma":[0.002370734,0.0560851,0.01593878,0.0003206369,0.001134974,0.0002616257,0.0003089875,0.01735366,0.8633915,0.001573101,0.04097192,0.0002889497],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.3744312,0.002995463,0.5209585,0.000295483,0.001089664,0.08738673,0.003677543,0.001167309,0.007998057],"genre_scores_gemma":[0.1773155,0.002129873,0.6700912,0.0002398086,0.00007825019,0.144303,0.001297439,0.0001492153,0.0043956],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.006655958,"threshold_uncertainty_score":0.02753419,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0556986850452427,"score_gpt":0.3261928244037718,"score_spread":0.2704941393585291,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}