{"id":"W2008190770","doi":"10.1002/chin.201345028","title":"ChemInform Abstract: Silver‐Catalyzed Ring‐Opening of Cyclopropenes: Preparation of Tertiary α‐Branched Allylic Amines.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Regioselectivity; Allylic rearrangement; Ring (chemistry); Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001369892,0.0003790205,0.0005499057,0.000116702,0.00006371786,0.00004727108,0.0005225262,0.000313136,0.008313881],"category_scores_gemma":[0.0001698847,0.0003603952,0.0002281578,0.0002177535,0.0001212587,0.001058816,0.0001928617,0.0002524125,0.0001769308],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001390523,"about_ca_system_score_gemma":0.0001120782,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002118366,"about_ca_topic_score_gemma":0.00002155322,"domain_scores_codex":[0.997516,1.089965e-7,0.001187409,0.0003493337,0.0005340328,0.0004130625],"domain_scores_gemma":[0.9975943,0.00008650107,0.0009587687,0.0008069259,0.0003900768,0.0001634334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007917565,0.00006928662,0.000197116,0.001241009,0.00006432248,0.00000121784,0.0014648,0.000002025354,0.8495885,0.00002758101,0.0005034591,0.1467616],"study_design_scores_gemma":[0.001003191,0.0000207847,0.00146052,0.0002352792,0.00004979244,0.00002601635,0.001299015,0.00005843281,0.9919655,0.00005194111,0.003457427,0.0003720827],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4971024,0.00007647527,0.000001180031,0.00001405142,0.00006036779,0.000280853,0.00001583002,0.0001027632,0.5023461],"genre_scores_gemma":[0.9884056,0.00004666412,0.0002355195,0.00002122138,0.0001115268,0.0001631375,0.0004052833,0.00005181048,0.01055924],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.4917868,"threshold_uncertainty_score":0.9998848,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.011022221970591,"score_gpt":0.2405933013106503,"score_spread":0.2295710793400593,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}