{"id":"W2008354775","doi":"10.1063/1.2834931","title":"The cyclic CO2 trimer: Observation of a parallel band and determination of an intermolecular out-of-plane torsional frequency","year":2008,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Trimer; Intermolecular force; Spins; Chemistry; Intramolecular force; Molecular physics; Crystallography; Molecule; Physics; Condensed matter physics; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005021866,0.0001848704,0.0001400272,0.0003412627,0.0002566852,0.0001420845,0.0003593029,0.0003353976,0.002497803],"category_scores_gemma":[0.0001716864,0.0001090033,0.0000885055,0.0002974408,0.0003236271,0.0001716,0.0002219124,0.0003207294,0.0001883821],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001644103,"about_ca_system_score_gemma":0.00008269596,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000633056,"about_ca_topic_score_gemma":0.0007674869,"domain_scores_codex":[0.9999222,0.00000317343,0.000001223436,0.00002900355,0.00002447191,0.00002004595],"domain_scores_gemma":[0.9998785,0.00001783335,0.00003501765,0.00001436335,0.00002133038,0.00003284159],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009446293,0.00001033823,0.0009064347,0.00004228654,0.00000867846,0.00009196458,0.00003460433,0.00006182872,0.9954827,0.000140426,0.0001681046,0.002958266],"study_design_scores_gemma":[0.00001603255,0.0002106733,0.03856985,0.000009429907,0.00002915108,0.001273586,0.0001159062,0.002184644,0.9544637,0.0002843147,0.002819846,0.00002285453],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945634,0.0005373457,0.001872305,0.00007346825,0.00002213818,0.00000642438,0.0001731257,0.00005202793,0.002699727],"genre_scores_gemma":[0.9979089,0.00008792482,0.001138792,0.00002936987,0.000007911823,0.000009998039,0.000182058,0.00001264888,0.0006224425],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002497803,"threshold_uncertainty_score":0.008355975,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01381839139601282,"score_gpt":0.2507587555172908,"score_spread":0.236940364121278,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}