{"id":"W2008442764","doi":"10.1063/1.3505321","title":"Isotope effects in liquid water by infrared spectroscopy. IV. No free OH groups in liquid water","year":2010,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"","keywords":"Infrared spectroscopy; Chemistry; Analytical Chemistry (journal); Infrared; Spectroscopy; Covalent bond; Methanol; Absorption spectroscopy; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003723914,0.0003192666,0.0005863087,0.00003691767,0.00006358075,0.00003589235,0.0007084305,0.0001051757,0.0002300405],"category_scores_gemma":[0.00003234544,0.0001691676,0.0002050725,0.0001334781,0.000198868,0.0002516296,0.0002989223,0.001539956,0.00006209129],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006144348,"about_ca_system_score_gemma":0.00002207836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006426351,"about_ca_topic_score_gemma":0.000002238596,"domain_scores_codex":[0.9981465,0.00007168226,0.0005986001,0.000197127,0.000330091,0.00065604],"domain_scores_gemma":[0.999048,0.0002168861,0.0001543236,0.0003642225,0.00009061406,0.0001259492],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001044411,0.0004014434,0.0003459666,0.00002385741,0.00006379902,0.000004661131,0.0008060453,0.000003693346,0.9932618,0.0007875983,0.003206576,0.00005011449],"study_design_scores_gemma":[0.001465702,0.0003353102,0.00002599911,0.00006310861,0.00004028588,0.000002832987,0.00004054377,0.00003089357,0.9435985,0.05290326,0.001255316,0.000238248],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954861,0.00006603431,0.0003280666,0.0007266995,0.0002996878,0.0001755448,0.00001036942,0.00001141099,0.00289611],"genre_scores_gemma":[0.9979429,0.00001290402,0.0002512771,0.0002067989,0.001475269,0.00001246954,0.00001673687,0.00003464404,0.00004701906],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05211567,"threshold_uncertainty_score":0.6898456,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00403434356438682,"score_gpt":0.2220909711748466,"score_spread":0.2180566276104598,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}