{"id":"W2008679055","doi":"10.1016/s0926-2040(03)00043-2","title":"Reorientation phenomena in imidazolium methyl sulfonate as probed by advanced solid-state NMR","year":2003,"lang":"en","type":"article","venue":"Solid State Nuclear Magnetic Resonance","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"Deutsche Forschungsgemeinschaft","keywords":"Imidazole; Solid-state nuclear magnetic resonance; Proton; Proton NMR; Ring (chemistry); Chemistry; Sulfonate; Carbon-13 NMR; Dipole; Limiting; Melting point; Coalescence (physics); Polarization (electrochemistry); Materials science; Chemical physics; Physical chemistry; Nuclear magnetic resonance; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002198858,0.000407909,0.000421708,0.00009164678,0.0001916183,0.00007518796,0.0003934354,0.0001233024,0.0009604299],"category_scores_gemma":[0.0001195829,0.0004465613,0.0000917941,0.0005175321,0.0001903954,0.000275785,0.0000831556,0.0004613918,0.0001799313],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002194049,"about_ca_system_score_gemma":0.00007425209,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006387333,"about_ca_topic_score_gemma":0.00002848282,"domain_scores_codex":[0.9971533,0.00006614151,0.0007238816,0.0008527848,0.0003793285,0.0008245793],"domain_scores_gemma":[0.9986051,0.00007431602,0.0002685049,0.0007287505,0.0001309178,0.0001924638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0005504503,0.0006696485,0.000273161,0.0002485391,0.00002141532,0.00006726076,0.003238292,0.002891548,0.6193311,0.01197535,0.003827531,0.3569057],"study_design_scores_gemma":[0.002090606,0.000195006,0.0003462115,0.0001219447,0.00001518122,0.00001615155,0.000510686,0.002196562,0.1070741,0.04029493,0.8463177,0.000820884],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9041666,0.00560319,0.001007408,0.0005812596,0.00007596193,0.001237563,0.000340057,0.0007174479,0.08627046],"genre_scores_gemma":[0.9445958,0.007684692,0.02040011,0.0008162601,0.00007073985,0.0007583228,0.000121092,0.0003162465,0.02523674],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8424902,"threshold_uncertainty_score":0.9999529,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006589890444804203,"score_gpt":0.2715115627288273,"score_spread":0.2649216722840231,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}