{"id":"W2008710702","doi":"10.1021/om700400x","title":"New Pincer-Type Diphosphinito (POCOP) Complexes of Nickel","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":192,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Pincer movement; Yield (engineering); Medicinal chemistry; Ligand (biochemistry); Acetonitrile; Alkylation; Metalation; Nickel; Cationic polymerization; Pincer ligand; Alkyl; Adduct; Acrylonitrile; Toluene; Polymer chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326067,0.0005225854,0.0003653916,0.0002751052,0.0002088654,0.0006603738,0.0006727112,0.0003791555,0.001122722],"category_scores_gemma":[0.0003644009,0.0002666586,0.00017162,0.0002334286,0.0002834988,0.0004556014,0.0006732691,0.0004266662,0.0004678756],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004717505,"about_ca_system_score_gemma":0.000189994,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004716612,"about_ca_topic_score_gemma":0.001076609,"domain_scores_codex":[0.9997391,0.00002971008,0.00002128868,0.00006488888,0.00009597411,0.00004900812],"domain_scores_gemma":[0.9999156,0.00001037516,0.00001914692,0.0000146323,0.00001382829,0.00002634038],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002389023,0.00003825325,0.0003520552,0.0003915119,0.00002483318,0.0003430327,0.0001316974,0.0004306147,0.989719,0.001113893,0.0003660097,0.006850302],"study_design_scores_gemma":[0.00002606441,0.0003052987,0.0007073884,0.00001561368,0.00002129134,0.000608916,0.00003265165,0.0005417284,0.9874542,0.000112229,0.01015716,0.00001747965],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9712698,0.002760459,0.00869503,0.0000983585,0.00006951878,0.0002099734,0.0004679069,0.0003045765,0.01612434],"genre_scores_gemma":[0.9847809,0.001370273,0.007273956,0.0001094232,0.00001781983,0.0001071394,0.0007336374,0.00009104485,0.005515631],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001122722,"threshold_uncertainty_score":0.003755867,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01746066325159712,"score_gpt":0.2480234419087939,"score_spread":0.2305627786571968,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}