{"id":"W2008713195","doi":"10.1021/ja3048656","title":"Highly Efficient Blue Phosphorescence from Triarylboron-Functionalized Platinum(II) Complexes of <i>N</i>-Heterocyclic Carbenes","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":248,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Queen's University","funders":"","keywords":"Phosphorescence; Chemistry; Platinum; Chelation; Electroluminescence; Solid-state; Photochemistry; Combinatorial chemistry; Polymer chemistry; Catalysis; Organic chemistry; Fluorescence; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001210388,0.0003738154,0.0002662696,0.0001648537,0.0001650687,0.0004548023,0.0003500037,0.0002841038,0.001498371],"category_scores_gemma":[0.0001452673,0.0001934535,0.0001351752,0.0001342605,0.0002176525,0.0002648131,0.000290429,0.0003298582,0.0004096901],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003820902,"about_ca_system_score_gemma":0.0001211269,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005591156,"about_ca_topic_score_gemma":0.001298461,"domain_scores_codex":[0.9998866,0.00001965962,0.000005524486,0.00002253583,0.00003194351,0.00003375024],"domain_scores_gemma":[0.9999468,0.00001195967,0.00001308766,0.000005178745,0.000008355086,0.00001454353],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005267797,0.000007687773,0.00004555396,0.000054417,0.000004766978,0.000044137,0.0000249572,0.00007462926,0.9974869,0.0002747488,0.0001352447,0.001794219],"study_design_scores_gemma":[0.000005866941,0.00003022447,0.0001774268,0.000002512807,0.000003200044,0.0000439828,0.000005193432,0.000148475,0.9986123,0.00002240899,0.0009454336,0.000002965318],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.977914,0.003129344,0.006335109,0.0001446413,0.00003736529,0.00002365053,0.0001988807,0.0002320416,0.01198487],"genre_scores_gemma":[0.9915038,0.001056702,0.003137949,0.00007746946,0.000009658065,0.00001730038,0.0001492817,0.00005995688,0.003987773],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001498371,"threshold_uncertainty_score":0.005012572,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009564471677690511,"score_gpt":0.2338098633363288,"score_spread":0.2242453916586383,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}