{"id":"W2008858698","doi":"10.1071/ch13209","title":"Preparation and Structures of Group 12 and 14 Element Halide–Carbene Complexes","year":2013,"lang":"en","type":"article","venue":"Australian Journal of Chemistry","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Carbene; Chemistry; Adduct; Hydride; Medicinal chemistry; Halide; Borohydride; Main group element; Reagent; Transmetalation; Polymer chemistry; Organic chemistry; Catalysis; Metal; Transition metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002398279,0.0003527852,0.0003995569,0.0003217928,0.0003566417,0.0004331787,0.001019227,0.0004096469,0.003026804],"category_scores_gemma":[0.0002955626,0.0002365613,0.00018351,0.0003617996,0.0002166455,0.000246833,0.0004698103,0.0006143753,0.0008043637],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009232514,"about_ca_system_score_gemma":0.0003639214,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001145757,"about_ca_topic_score_gemma":0.002405614,"domain_scores_codex":[0.9997167,0.00003213689,0.00002213943,0.00006205712,0.00008790242,0.0000789449],"domain_scores_gemma":[0.9998937,0.00001239252,0.00001598065,0.00002122968,0.00002850759,0.00002822635],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005886211,0.0002371382,0.000547769,0.0004407202,0.00007063302,0.0002696415,0.0003378085,0.002180032,0.9772218,0.004242714,0.001163131,0.01269999],"study_design_scores_gemma":[0.0001568679,0.0009803141,0.001233573,0.00002157659,0.00004026827,0.0002257233,0.00006456101,0.001598922,0.9731833,0.0002122463,0.0222368,0.00004581752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9732481,0.002297357,0.006201447,0.0001063723,0.0000621655,0.0003509519,0.0007142282,0.0001813653,0.016838],"genre_scores_gemma":[0.9838657,0.001057467,0.005898952,0.00005988899,0.0000132878,0.0001661427,0.001184586,0.00005889357,0.007695226],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003026804,"threshold_uncertainty_score":0.0101257,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.021492505400979,"score_gpt":0.298106281602162,"score_spread":0.2766137762011829,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}