{"id":"W2009140699","doi":"10.1246/bcsj.75.2415","title":"Formation of Two Chromium(III) Dithiocarbamates from Cr(VI) in Solvent Extraction System and Origin of Oxygen Atom in Bis(1-pyrrolidinecarbodithioato)[1-pyrrolidinecarbothio(thioperoxoato)]chromium(III)","year":2002,"lang":"en","type":"article","venue":"Bulletin of the Chemical Society of Japan","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Paul University","funders":"","keywords":"Chemistry; Chromium; Oxygen atom; Solvent; Solvent extraction; Oxygen; Extraction (chemistry); Chromium Compounds; Atom (system on chip); Inorganic chemistry; Molecular oxygen; Photochemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001348925,0.0003003024,0.0001599188,0.000232646,0.0001416162,0.0002379318,0.0001803197,0.0003401512,0.0006926219],"category_scores_gemma":[0.0002810905,0.0001696408,0.0001579641,0.0001591057,0.0001875807,0.0001971854,0.0001769804,0.0003159359,0.0002059292],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001632659,"about_ca_system_score_gemma":0.0001863165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005024083,"about_ca_topic_score_gemma":0.001043356,"domain_scores_codex":[0.9998267,0.00002509689,0.00001006218,0.00004977495,0.00005986748,0.00002859602],"domain_scores_gemma":[0.9998339,0.00003828201,0.00004345592,0.00001542838,0.00003884224,0.0000299497],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000231469,0.000003398857,0.00006623414,0.00001605629,0.000002136309,0.00002138561,0.000007220428,0.00000775895,0.9995081,0.00000986811,0.000004088056,0.0003305012],"study_design_scores_gemma":[0.000002580063,0.00003040387,0.0007493233,0.000001262274,0.000004067476,0.00003744697,0.00000509447,0.000145214,0.9988031,0.000005398818,0.0002147336,0.000001289534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910706,0.0006785716,0.007151461,0.00004427593,0.00002260078,0.00004819026,0.0001721161,0.00009398042,0.0007181468],"genre_scores_gemma":[0.9896027,0.0002901434,0.007748961,0.00003564163,0.000005670734,0.00002542727,0.0002723992,0.00003346446,0.001985495],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006926219,"threshold_uncertainty_score":0.002317071,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0136912427863349,"score_gpt":0.2132127722556906,"score_spread":0.1995215294693557,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}