{"id":"W2009557533","doi":"10.1021/ol048240x","title":"Chiral [2.2.2] Dienes as Ligands for Rh(I) in Conjugate Additions of Boronic Acids to a Wide Range of Acceptors","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":283,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Conjugate; Diene; Ligand (biochemistry); Combinatorial chemistry; Selectivity; Stereochemistry; Medicinal chemistry; Catalysis; Organic chemistry; Receptor; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006211151,0.0007188867,0.0004381038,0.0002508852,0.0002110641,0.0005774648,0.0005720058,0.000552835,0.001178538],"category_scores_gemma":[0.000332104,0.000300825,0.0001631884,0.0002257222,0.0004223855,0.0005282797,0.0003858268,0.0004692998,0.0006793439],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004204622,"about_ca_system_score_gemma":0.0002205159,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004152599,"about_ca_topic_score_gemma":0.00128378,"domain_scores_codex":[0.9996635,0.0001414362,0.00001833265,0.00004530214,0.00006258454,0.00006882777],"domain_scores_gemma":[0.999873,0.00003342466,0.00002803324,0.00001838493,0.00001783203,0.00002926214],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002927942,0.00005125281,0.0001460068,0.0001550152,0.00001126283,0.0001953543,0.00009098308,0.001289476,0.9917755,0.002152974,0.0001965683,0.003642818],"study_design_scores_gemma":[0.00001832032,0.000154699,0.0000838748,0.000005015866,0.000007215536,0.00008024735,0.000009456247,0.0008270594,0.9972776,0.00005054886,0.001478567,0.000007471453],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9742959,0.002601262,0.01053485,0.0002117266,0.00006155246,0.000107306,0.0001945584,0.0002328446,0.01176009],"genre_scores_gemma":[0.9882808,0.001194498,0.006625073,0.0001240098,0.00001922621,0.0000436211,0.0001258859,0.00004230072,0.003544531],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001178538,"threshold_uncertainty_score":0.003942609,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008336763630776161,"score_gpt":0.2520217438138481,"score_spread":0.2436849801830719,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}