{"id":"W2009654960","doi":"10.1021/jo010570x","title":"Synthesis of Di- to Hexasaccharide 1,2-Linked β-Mannopyranan Oligomers, a Terminal S-Linked Tetrasaccharide Congener and the Corresponding BSA Glycoconjugates","year":2001,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Tetrasaccharide; Chemistry; Stereochemistry; Disaccharide; Trisaccharide; Glycoconjugate; Glycosylation; Oligosaccharide; Bromide; Residue (chemistry); Protecting group; Total synthesis; Glycoside; Glycosyl donor; Hapten; Nitrile; Organic chemistry; Biochemistry; Polysaccharide; Antigen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009847496,0.0003946256,0.0002269118,0.0001182203,0.0001216108,0.0002346494,0.000138539,0.0001607626,0.0009885535],"category_scores_gemma":[0.0001018969,0.0001386995,0.0001633316,0.0001685431,0.0001087386,0.0001620637,0.0001931253,0.0003545611,0.0004482609],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002474977,"about_ca_system_score_gemma":0.0003174377,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003735226,"about_ca_topic_score_gemma":0.000729399,"domain_scores_codex":[0.9999269,0.0000134544,0.000006350005,0.00001808493,0.0000171174,0.00001809334],"domain_scores_gemma":[0.9999268,0.000006776648,0.00001931972,0.00001215724,0.00001078377,0.00002425562],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003201687,0.00001709094,0.00008580006,0.00003063871,0.000005136361,0.00003883333,0.00001176452,0.0001411898,0.9970568,0.0001487731,0.00002370101,0.002408291],"study_design_scores_gemma":[0.000007848549,0.0001859827,0.0008999436,0.000002777296,0.00001217769,0.0001340887,0.000008516425,0.0003062234,0.995513,0.00004275665,0.00288288,0.000003740841],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9846049,0.001364052,0.01020725,0.00007264182,0.00003220935,0.00007328931,0.0003880411,0.0001175784,0.00314019],"genre_scores_gemma":[0.9683434,0.001633666,0.02264896,0.00009668686,0.00001031899,0.00006419583,0.001001539,0.0000572428,0.00614394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009885535,"threshold_uncertainty_score":0.003306985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0106529640392051,"score_gpt":0.2243495725152738,"score_spread":0.2136966084760687,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}