{"id":"W2009800845","doi":"10.1002/chin.200416113","title":"Palladium‐Catalyzed Sequential Alkylation—Alkenylation Reactions: New Three‐Component Coupling Leading to Oxacycles.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Palladium; Alkylation; Catalysis; Component (thermodynamics); Coupling reaction; Coupling (piping); Organic chemistry; Combinatorial chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001774779,0.0007203093,0.000328657,0.0002297195,0.0002769072,0.0004910977,0.0005056442,0.000391769,0.003916844],"category_scores_gemma":[0.0002310835,0.0003512441,0.000186324,0.0003664919,0.0003201218,0.0007833958,0.0006527434,0.001009404,0.001553256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003365679,"about_ca_system_score_gemma":0.0004037728,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004621959,"about_ca_topic_score_gemma":0.001816975,"domain_scores_codex":[0.999874,0.00001427736,0.000008851158,0.0000349036,0.0000192852,0.00004864694],"domain_scores_gemma":[0.9999408,0.00001226668,0.000008606904,0.00001238913,0.00000767437,0.00001833443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005993354,0.0002360423,0.0002847838,0.0008110105,0.00006922207,0.0007218727,0.0003688073,0.00146553,0.9026884,0.009281825,0.003737389,0.07973567],"study_design_scores_gemma":[0.00009873406,0.0003709581,0.0006258219,0.00002536085,0.00005140828,0.0004802335,0.00006319763,0.001160897,0.9527865,0.001313335,0.0429964,0.00002714392],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7190776,0.01877255,0.1633491,0.0009710385,0.001265444,0.0006503834,0.001662959,0.001649671,0.09260131],"genre_scores_gemma":[0.9361823,0.008614059,0.03149831,0.0001964096,0.00004649986,0.0001580394,0.0007115237,0.0001390317,0.02245374],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003916844,"threshold_uncertainty_score":0.01310313,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04073131630149437,"score_gpt":0.3000105343268943,"score_spread":0.2592792180254,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}