{"id":"W2009820791","doi":"10.1039/b908726e","title":"An investigation of the influence of R on the abilities of the polar monomers CH2CH(CH2)8OR (R = Me, PhCH2, Ph3C, Me3Si, Ph3Si) to participate in O- rather than η2-coordination to metallocene alkene polymerization catalysts; an unanticipated role for ether oxygen coordination in promoting polymerization","year":2009,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Monomer; Chemistry; Ethylene; Copolymer; Catalysis; Polymerization; Alkene; Polymer chemistry; Post-metallocene catalyst; Steric effects; Alkyl; Ether; Metallocene; Polar; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001957631,0.0002205935,0.0001714275,0.00007385899,0.0001033977,0.0002074839,0.0002251266,0.0002572013,0.001447724],"category_scores_gemma":[0.0004457371,0.0001038077,0.0001208799,0.0001007747,0.0002399169,0.0002356642,0.0001357735,0.0003211186,0.0002757359],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000149299,"about_ca_system_score_gemma":0.0001336892,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007979437,"about_ca_topic_score_gemma":0.001014482,"domain_scores_codex":[0.9998766,0.0000241457,0.000006580971,0.00002664124,0.00002994447,0.00003616094],"domain_scores_gemma":[0.9997889,0.0001069938,0.00005017688,0.0000168711,0.00001877315,0.00001824387],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003804401,0.00005605347,0.0003435026,0.00008856611,0.00001180581,0.00006935575,0.00005538299,0.0001869665,0.9958214,0.00008912354,0.00005106268,0.002846394],"study_design_scores_gemma":[0.00001179876,0.0004744345,0.002225083,0.000003255585,0.00001189391,0.0000909435,0.00002239942,0.000337938,0.996074,0.00001974915,0.0007236581,0.000004998436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961432,0.0006907718,0.0005930713,0.00002822722,0.000005071134,0.00002014123,0.0001441668,0.00002635768,0.002349159],"genre_scores_gemma":[0.9984366,0.0003853929,0.000502093,0.00001448007,0.000003517695,0.000006660932,0.00006735546,0.000008295943,0.0005755732],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001447724,"threshold_uncertainty_score":0.004843175,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01564112104821181,"score_gpt":0.2484271725097779,"score_spread":0.2327860514615661,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}