{"id":"W2009895946","doi":"10.1021/ac0343634","title":"Matrix Effects Affecting the Indirect Calibration of the Static Headspace-Gas Chromatographic Method Used for Dissolved Gas Analysis in Dielectric Liquids","year":2003,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Hydro-Québec; Institut National de la Recherche Scientifique","funders":"","keywords":"Chemistry; Solubility; Dissolution; Matrix (chemical analysis); Mineral oil; Dielectric; Chemical polarity; Gas chromatography; Phase (matter); Analytical Chemistry (journal); Chromatography; Thermodynamics; Organic chemistry; Dipole; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.003296564,0.001461305,0.0005129295,0.0009513126,0.000823797,0.00125164,0.001164592,0.001602111,0.001343476],"category_scores_gemma":[0.006980068,0.0007493533,0.0006645341,0.000899183,0.0009774431,0.0007294178,0.001299758,0.001406533,0.001159242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007662365,"about_ca_system_score_gemma":0.001701744,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002922066,"about_ca_topic_score_gemma":0.005166608,"domain_scores_codex":[0.9952136,0.001049654,0.0002331922,0.001165119,0.002076711,0.000261639],"domain_scores_gemma":[0.9975914,0.0009583403,0.0002616463,0.0003772773,0.0007384661,0.00007294407],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001454878,0.00003378,0.001125009,0.0001315559,0.00002746167,0.00006339124,0.00009278971,0.0002341566,0.9938701,0.0002265257,0.00007892621,0.003970663],"study_design_scores_gemma":[0.000005723526,0.0001415341,0.001725014,0.00001427106,0.00002741647,0.0001511667,0.00004984396,0.002577564,0.9935542,0.0001057969,0.001635395,0.00001218215],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.568773,0.006161138,0.4141197,0.0003333676,0.0008642446,0.0009184332,0.001250352,0.002033552,0.005546129],"genre_scores_gemma":[0.7645445,0.00447987,0.2233668,0.000459523,0.00007559024,0.001142305,0.001327438,0.0005698474,0.004034265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003296564,"threshold_uncertainty_score":0.01743412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009913078116543069,"score_gpt":0.2764090839748091,"score_spread":0.266496005858266,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}