{"id":"W2009948597","doi":"10.1021/om9000814","title":"Laser Flash Photolysis Studies of Some Dimethylgermylene Precursors","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Flash photolysis; Cyclohexane; Microsecond; Photochemistry; Reaction rate constant; Quenching (fluorescence); Germane; Yield (engineering); Photodissociation; Trimethylsilyl; Analytical Chemistry (journal); Kinetics; Fluorescence; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009659284,0.000230072,0.0001445962,0.0001473791,0.0001181516,0.0001490124,0.0001825904,0.0001900143,0.002082849],"category_scores_gemma":[0.0001604942,0.0001135221,0.0001516686,0.0001640923,0.000107932,0.0001605905,0.0001013992,0.000267004,0.0002564731],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003564962,"about_ca_system_score_gemma":0.000144305,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000868295,"about_ca_topic_score_gemma":0.001207834,"domain_scores_codex":[0.9999447,0.000005218574,0.000002911335,0.00001398709,0.00001711049,0.00001607794],"domain_scores_gemma":[0.9999337,0.000021819,0.00001666054,0.000006487431,0.00001181234,0.000009474961],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003223676,0.000007038352,0.0001269476,0.00004048739,0.000002994639,0.00005821994,0.00003060994,0.000104164,0.9983774,0.00005585678,0.00002332631,0.001140661],"study_design_scores_gemma":[0.000003370341,0.0001565039,0.001468212,0.000002412499,0.000005082263,0.00006915435,0.00002215417,0.0002846624,0.9972275,0.000009810362,0.0007477893,0.0000033601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969451,0.0006293079,0.001075604,0.00002109545,0.000005933603,0.00001195708,0.0001281295,0.00002162725,0.001161236],"genre_scores_gemma":[0.9953718,0.0008024198,0.001666308,0.00002164669,0.000003949696,0.00001351235,0.0002456218,0.00001547557,0.001859352],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002082849,"threshold_uncertainty_score":0.006967843,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02841298979774612,"score_gpt":0.2723861012301123,"score_spread":0.2439731114323661,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}